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How is anhydrous magnesium chloride prep...

How is anhydrous magnesium chloride prepared from magnesium chloride hexahydrate?

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Magnesium chloride hexahydrate on heating gets hydrolysed by its own water of crystallisation and hence anhydrous `MgCl_(2)` cannot be prepared by heating `MgCl_(2).6H_(2)O`.
`Ngcl_(2).6H_(2)Ooverset(Delta)(rarr)MgO+2HCl+5H_(2)O`
However,if `MgCl_(2).6H_(2)O` is heated in atmoshphere of `HCl` gas, it prevents the above hydrolysis reaction and `MgCl_(2).6H_(2)O` loses its water molecule of crystallisation.
`MgCl_(2).6H_(2)Ooverset(HCl gas)underset(Delta)(rarr)MgCl_(2)+6H_(2)O`
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Hydrated calcium chloride when fused loses water of crystallization to form anhydrous calcium chloride but anhydrous magnesium chloride cannot be prepared by heating magnesium chloride hexahydrate . Why so ?

From hydrated magnesium chloride, anhydrous magnesium chloride can be prepared by heating the hexahydrate in :

Knowledge Check

  • Anhydrous aluminium chloride is prepared by

    A
    Dissolving aluminium metal in conc. HCl
    B
    By heating a mixture of alumina with chlorine
    C
    By heating a mixture of alumina and carbon with dry chlorine
    D
    By heating alumina with dry HCl
  • Anhydrous ferric chloride is prepared by

    A
    Heating hydrated ferric chloride at a high temperature in a stream of air.
    B
    Heating metallic iron in astream of dry chlorine gas
    C
    Reaction of ferric oxide with HCl
    D
    Reaction of metallic iron with HCl
  • Anhydrous ferric chloride is prepared by

    A
    dissolving `Fe(OH)_3` in concentrated `HCl`
    B
    dissolving `Fe(OH)_3`, in dilute HCI
    C
    passing dry HCl over heated iron scrap
    D
    passing dry `Cl_2`, gas over heated iron scrap.
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    Anhydrous feric chloride is prepared by:

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    Statement-1:Sodium chloride is added during electrolysis of fused anhydrous magnesium chloride. Statement-2:Anhydrous magnesium chloride is obtained by heating hydrated magnesium chloride, MgCl_2. 6H_2O

    Anhydrous ferric chloride is prepared by :