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The +1 oxidation state is more stable th...

The `+1` oxidation state is more stable than `+3` oxidation state for thallium. Give reason.

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Electronic configuration of thallium is `[Xe]4f^(14) 5d^(10) 6s^(2) 5p^(1)`. Due to the presence of fully filled lesser shieling `4f^(14)` and `5d^(10)` orbitals between the valence shell and noble gas core, the valence shell electrons are more tightly bound of the nucleus , hence, it is difficult to unpair `6s^(2)` effect. This gives rise to inert pair effect. Therefore, `6s^(2)` electrons are less reactive and do not participate in the chemical bond formation. Hence, in thallium, `+1` oxidation state in more stable than `+3` oxidation state.
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CENGAGE CHEMISTRY-P-BLOCK GROUP 13 - BORON FAMILY-Ex 6.1 (Subjective)
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  2. The +1 oxidation state is more stable than +3 oxidation state for thal...

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  3. Aluminium chloride exists as dimer. Give reason.

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  4. Why boron halides do not exists as a dimer. While AlCl(3) exists as Al...

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  5. Give reaction for the following : (a) In (III) is more stable than i...

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  6. Why boron and aluminium tend to for, covalent compounds ?

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  7. Molten aluminium bromide is a poor conductor of electricity. Give reas...

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  8. Why B-X bond distance in BX(3) is shorter than theoretically expected ...

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  9. Boric acid can be titrated against sodium hydroxide using phenolphthal...

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  10. Which one is more soluble in diethyl ether : anhydrous AlCl(3) or hydr...

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  11. How is boron obtained from borax ? Give the chemical reactions involve...

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