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Compounds wich readily unfergo hydrolysi...

Compounds wich readily unfergo hydrolysis are :

A

`CCl_4`

B

`BCl_3`

C

`SiCl_4`

D

`CF_4`

Text Solution

Verified by Experts

The correct Answer is:
B, C
` BC l_3` and ` SiCl_4` have vacant orbital of suitable enrgy to acept a pair of electron from `H_2O` molecule and thus easily undergo hydroysis, whereas in ` CC l_4` and ` CF_(4+)` due to the absence of low lying d-orbitals , hdrolysis is not possible .
` BC l_3 + 3 H_2O rarr B(OH)_3 +3HCl`
`S iCl_4+ 4H_2O rarr H_4SiO_4 +4HCl`.
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Knowledge Check

  • Substances which readily undergo hydrolysis are

    A
    `AlCl_(3)`
    B
    `BCl_(3)`
    C
    `SiCl_(4)`
    D
    `PbCl_(4)`

  • The compounds that undergo hydrolysis readily is/are

    A
    `TiCl_(4)`
    B
    `VCl_(5)`
    C
    `FeCl_(3)`
    D
    `CaCl_(2)`

  • The compound which readily undergoes decaroxylation is

    A
    `HOOC-CH_(2)-COOH`
    B
    `C_(6)H_(5)-COOH`
    C
    `HOOC-(CH_(2))_(4)-COOH`
    D
    `CH_(2)-CH_(2)-CH_(2)-COOH`

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    Which of the following compounds will be most readily dehydrated ?

    Which of the following compounds are readily soluble in water ?

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