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Assuming 2s, 2p mixing is NOT operative ...

Assuming `2s, 2p` mixing is NOT operative , the paramagnetic species among the following is

A

`Be_(2)`

B

`B_(2)`

C

`C_(2)`

D

`N_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

As it has two unpaired electrons
`Be_(2)=sigma1s^(2)sigma^(**)1s^(2)sigma2s^(2)sigma^(**)2s^(2)`
`B_(2)=sigma1s^(2)sigma^(**)1s^(2)sigma2s^(2)sigma^(**)2s^(2)pi2p_(y)^(1)pi2p_(x)^(1)`
`C_(2)=sigma1s^(2)sigma^(**)1s^(2)sigma2s^(2)sigma^(**)2s^(2)pi2p_(y)^(2)pi2p_(x)^(2)`
`N_(2)=sigma1s^(2)sigma^(**)1s^(2)sigma2s^(2)sigma^(**)2s^(2)pi2p_(y)^(2)pi2p_(x)^(2)sigma2p_(z)^(2)`
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Knowledge Check

  • Assuming 2s - 2p mixing is NOT operative , the paramagnetic among the following is

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