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Describe the action of heat on the follo...

Describe the action of heat on the following compounds :
(a) Ammonium nitrate
(b) Ammonium nitrite
( c) Ammonium chloride.
(d) Ammonium dichromate
( e) Orthophosphoric acid
(f) Phosphrous acid
(g) Hypophosphorous acid
(h) Copper nitrate.

Text Solution

Verified by Experts

(a) `NH_4 NO_3 overset (Delta) rarr N_2 O + 2 H_2 O`
(b) `NH_4 NO_2 overset (Delta) rarr N_2 + 2 H_2 O`
( c) `NH_4 Cl rarr NH_3 + HCl`
(d) `(NH_4)_2 Cr_2 O_7 overset (Delta) rarr N_2 + Cr_2 O_3 + 4 H_2 O`
( e) `2 H_3 PO_3 overset (Delta) rarr H_4 P_2 O_7 + H_2 O`
(f) `4H_3 PO_3 overset (Delta)rarr 3 H_3 PO_4 + PH_3`
(g) `2 H_3 PO_2 overset (Delta) rarr H_3 PO_4 + PH_3`
(h) `2 Cu(NO_3)_2 overset (Delta) rarr 2 CuO + 2 NO_2 + O_2`.
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CENGAGE CHEMISTRY-P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY-Concept Application Exercises 2.1 (Subjective)
  1. Why nitrogen is inert at room temperature ?

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  2. Why BiH3 is strongest reducing agent amongst group 15 hydrides ?

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  3. Why nitrogen trihalide cannot be oxidised to pentahalide whereas phosp...

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  4. NO is paramagnetic, while NO^(oplus) is diamagnetic.

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  5. Which of the following acts as reducing agent and why ? H3 PO3 or H3 P...

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  6. Nitrogen is a gas, while other members of group 15 are solids. Why ?

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  7. Why commercial HNO3 is generally yellow in colour ?

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  8. Nitric acid acts as an oxidising agent while nitrous acid can act both...

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  9. Which is more basic and why ? NF3 or NH3.

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  10. What is the chemistry of Holme's signal ?

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  11. Write complete balanced reactions for the following : (a) Red phosph...

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  12. Describe the action of heat on the following compounds : (a) Ammoniu...

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  13. Concentrated nitric acid can be stored in aluminium container. Give re...

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  14. Why calcuim cyanamide can be used as a fertiliser ?

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  15. Describe being odd electron molecule, NO is colourless. Explain.

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  16. Give reason : Urea is better nitrogenous fertiliser than ammonium sulp...

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  17. Mg3 N2 on reaction with water gives off NH3, but MgCl2 on reaction wit...

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  18. Oxides of nitrogen have open chain structures while those of phosphoro...

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  19. Illustrate, how copper gives different products on reaction with HNO3.

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  20. Give the names of formulae of the compounds described below : (a) A ...

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