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The BCl3 is a polar molecule whereas NCl...

The `BCl_3` is a polar molecule whereas `NCl_3` is pyramidal because

A

`N-Cl` bond is more covalent than `B-Cl` bond

B

`B-Cl` bond is more polar than `N-Cl` bond

C

Nitrogen atom is smaller than boron

D

`BCl_3` has no lone pair but `NCl_3` has a lone pair of electron.

Text Solution

Verified by Experts

The correct Answer is:
D
`BCl_3` is `sp^3` hybridised hence planar whereas `NCl_3` is `sp^3` hybridised with one `1p`, hence is pyramidal.
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CENGAGE CHEMISTRY-P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY-Exercises (Single Correct)
  1. Red phosphorus is less reactive than yellow phosphorus because

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  2. Aqua regia is

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  3. The number of steps, in which orthophosphoric acid is ionised, are

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  4. Phosphorous is usually extracted from

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  5. PCl5 is kept in well stopered bottles because

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  6. The BCl3 is a polar molecule whereas NCl3 is pyramidal because

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  7. N2 forms NCl3 whereas P can form both PCl3 and PCl5. Why ?

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  8. Cl-P-Cl bond angles in PCl5 molecule are

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  9. Hyarolysis of NCl3 gives NH3 and X. Which of the following is X ?

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  10. Chlorine reacts with excess of ammonia to form.

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  11. The following are some statements related to group 15 hydrides. (i) ...

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  12. The atomicity of phosphorus is X and the P-P-P bond angle is Y. What a...

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  13. The reaction of P with X leads selectively to P4 O6. X is

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  14. Atoms in P4 molecule of white phosphorus are arranged regularly in the...

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  15. Phosphine, acetylene and ammonia can be formed by treating water with

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  16. The cyanide ion CN and N(2) are isoelectronic, but in contrast to CN^(...

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  17. Nitrogen forms N(2) but phosphorous when forms P(2) gets readily conve...

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  18. In NO(3)^(-) ion, the number of bond pair and lone pair of electrons o...

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  19. Blue liquid which is formed at - 30^@ C by mixing of two gases is.

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  20. The element which forms oxides in all oxidation states +1 to +5 is.

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