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Write the structure and name of the foll...

Write the structure and name of the following and their ionisation isomers
`[Pt (NH_(3))_(3)(NO_(2))]CI`
(ii) `[Pt (NO_(2))(H_(2)O)(NH_(3))_(2)]Br`
(iii) `[Co(NH_(3))_(5)Br]SO_(4)` .

Text Solution

Verified by Experts

The ionisation isomer of `[Pt(NH_(3))_(3)(NO_(2))]CI(A)` is
`[Pt (NH_(3))_(3)CI]NO_(2)(B)` The structures and names of these isomers are give as
`(A)` implies Triamminenitroplatinum(II)chloride
`(B)`implies Triamminechloridoplatinum (II) nitrite
(ii) The ionisation isomer of `[Pt(NO_(2))(H_(2)O)(NH_(3))_(2)]Br`
`(C )` is `[Pt(H_(2)O)(NH_(3))_(2)Br]NO_(2)(D) The structures and names of these isomers are given as
`(C )implies Diammineaquanitroplatinum (II) bromide
`(D)implies` Diammineaquabromidoplatium (II) nitrite
(iii) The ionisation isomer of `[Co(NH_(3))_(5)Br]SO_(4)(E)` is
`[Co(NH_(3))_(5)SO_(4)]Br(F)` The structure names of these isomers are given as
`(E)implies Pentamminebromidocobalt (III) sulphate
(F)implies pentamminesulphatocobalt (III)bromide .
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