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Coordination compounds plays many import...

Coordination compounds plays many important roles in animals and plants. The are essential in the storage and transport of oxygen as electrons transfer agents as catalysts and in photosynthesis Wide range of application in daily life takes place through formation of complexes Photographic fixing qualitative and quantitative analysis purification of water metallurgical extraction are some specific worth mentioning
Arrange of the following in order of decreasing number of unpaired electrons
(I) `[Fe(H_(2)O))_(6)]^(2+)`
(II) `[Fe(CN)_(6)]^(3-)`
(III) `[Fe(CN)_(6)]^(4-)`
(IV) `[fe(H_(2)O)_(6)]^(3+)`
(a) IV,I,II,III
(b) `I,II,III,IV`
(c) `III,II,IIV`
(d) II,III,I,IV` .

A

`IV,I,II,III`

B

`I,II,III,IV`

C

`III,II,I,IV`

D

`II,III,I,IV`

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The correct Answer is:
A
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Coordination compounds plays many important roles in animals and plants. The are essential in the storage and transport of oxygen as electrons transfer agents as catalysts and in photosynthesis Wide range of application in daily life takes place through formation of complexes Photographic fixing qualitative and quantitative analysis purification of water metallurgical extraction are some specific worth mentioning The complex [Fe(H_(2)O)_(5)NO]^(2+) is formed in the brown ring test for nitrates when freshly prepared FeSO_(4) soultion is added to aqueous solution of NO_(3)^(Θ) followed by addition of conc. H_(2)SO_(4) Select correct statement about this complex (a) Colour change is due to charge transfer (b) It has iron in +1 oxidation state and nitrosyl as NO^(o+) (c ) It has magnetic moment of 3.87BM confirming three unpaired electrons in Fe (a) All the above are correct statements .

Coordination compounds plays many important roles in animals and plants. The are essential in the storage and transport of oxygen as electrons transfer agents as catalysts and in photosynthesis Wide range of application in daily life takes place through formation of complexes Photographic fixing qualitative and quantitative analysis purification of water metallurgical extraction are some specific worth mentioning Cu^(2+) and Cd^(2+) both are precipitated as sulphides on passing H_(2)S gas in dil HCI medium However, precipitation of Cu^(2+) is prevented by (a) Adding excess of K_(4)[Fe(CN)_(6)] when Cd^(2+) is only precipitated (b) Adding excess of KNC when Cu^(2+) for stable complex [Cu(CN)_(4)]^(3-) and Cd^(2+) forms unstable complex [Cd(CN)_(4)]^(2-) (c ) All of the above

Arrange the following compounds in order of decreasing acidity :

Which of the following complex is with lowest number of unpaired electron

CENGAGE CHEMISTRY-COORDINATION COMPOUNDS-Exercises Single Correct (Hybridisation , Magnetic And Optical Properties )
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  2. Which of the folliwng is paramagnetic ? .

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  3. The pair in which both species have same magnetic moment (spin only va...

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  4. Select the correct order of magnetic moment (inBM) from the folliwng o...

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  5. Which of the pair of complex compounds are tettrahedral as well as dia...

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  6. Which of the following has a square planar geometry? .

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  7. Among [Ni(CO)(4)],[Ni(CN)(4)]^(2-) and [NiBr(4)]^(2-) species, the hyb...

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  8. Coordination compounds plays many important roles in animals and plant...

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  9. A substance which is not paramagnetic is .

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  10. Which of the following statements is correct ?

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  11. An aqueous solution of titanium bromide shows zero magnetic moment. As...

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  12. Geometry, hybridisation and magnetic moment of the ions [Ni(CN)(4)]^(2...

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  13. The correct order of magnetic moment (spin values in is . (Atomic num...

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  14. A square planar complex is formed by hybridisation of which atomic ori...

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  15. The colour of a complex compound is due to .

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  16. If a transition-metla compound absorbs violet-indigo radiation in the ...

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  17. Transition metal compounds are usually coloured This is due to the ele...

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  18. Which of the following compound is not coloured ?

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  19. The colour of Cu^(o+) compounds is .

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