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A metal complex having composition Cr(NH...

A metal complex having composition `Cr(NH_(3))_(4)CI_(2)` Br has been isolated in two forms `A` and `B` The `A` reacts with `AgNO_(3)` to give a white precipitate readily soluble in dilute queous ammonia, whereas `B` gives a pale-yellow precipitate soluble in concentrated ammonia Write the formula of `A` and `B` and state the hybridisation of chromium in each. Calculate their magnetic moment (spin only value) .

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To solve the problem, we need to identify the two forms of the chromium complex, determine their formulas, state the hybridization of chromium in each, and calculate their magnetic moments. ### Step 1: Identify the Complexes A and B 1. **Complex A**: - It reacts with AgNO₃ to give a white precipitate that is soluble in dilute aqueous ammonia. - This indicates that the chloride ion (Cl⁻) is outside the coordination sphere. - Therefore, the formula for complex A is: ...
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A metal complex having composition Cr(NH_(3))_(4)CI_(2)Br has been isolated in two forms A and B. The form A reacts with AgNO_(3) to give a white precipitate readily soluble in dilute aqueous ammonia whereas B gives a pale yellow precipitate soluble in concentrated ammonia. (i) Write the formulae of isomers A and B. (ii) State the hybridisation of chromium in each of them. (iii) Calculate the magnetic moment (spin only) of the isomer A.

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