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Knowing the electron gain enthalpy value...

Knowing the electron gain enthalpy values for `O rarr O^(Ө)` and `O rarr O^(2-)` as `- 141 kJ mol^-1` and `+ 702 kJ mol^-1` respectively, how can you account for the formation of a large number of oxides having `O^(2-)` species and not `O^(Ө)` ?

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Formation of `MO_2` and `MO` involves the following steps:
`M_(g)overset(triangle_iH_l)toM^(o+)overset(triangle_iH_2)toM^(2+)`
`Ooverset(triangle_(eg)H_l)toO^(ɵ)underset("Energy")overset("Lattice")toM^(2+)(O^(ɵ))_(2(s))`.
`M^(2+)+O^(2-)underset("energy")overset("lattice")toM^(2+)O^(2-)`
(i). `O^(2-)` has a stable noble gas configuration.
(ii). Due to higher charge on `O^(2-)` than on `O^(ɵ)` ions, tha lattice energy released during the formation of oxides containing `O^(2-)` ion is much larger than during the formation of oxides containing `O^(ɵ)` ion. Hence formation of oxides containing `O^(2-)` species is energetically more favourable than oxides containing `O^(ɵ)` species.
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CENGAGE CHEMISTRY-APPENDIX INORGANIC VOLUME 2-Exercises
  1. Justify the placement of O,S,Se,Te and Po in the same group of the per...

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  2. Why is dioxygen a gas but sulphur a solid?

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  3. Knowing the electron gain enthalpy values for O rarr O^(Ө) and O rarr ...

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  4. Which aerosols deplete ozone?

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  5. How is SO2 an air pollutant?

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  6. Why are halogens strong oxidising agents ?

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  7. Explain why fluorine forms only one oxoacid, HOF.

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  8. Although chlorine and oxygen have nearly same electronegativity yet on...

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  9. Write two uses of ClO2.

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  10. Why are halogens coloured?

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  11. Write the reaction of F2 and Cl2 with water.

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  12. How can you prepare Cl2 from HCl and HCI from Cl2? Write reactions onl...

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  13. What inspired N. Bartlett for carrying out reaction between Xe and PtF...

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  14. What are the oxidation states of phosphorus in the following: (i)H(3...

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  15. Write balanced equation for the following: (i). NaCl is heated with ...

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  16. With what neutral molecule is ClO^(ɵ) isoelectronic Is that molecule a...

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  17. How are XeO3 and XeOF4 prepared?

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  18. Arrange the following in the order of property indicated for each set:...

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  19. Which one of the following does not exist? (i). XeOF4 (ii). NeF2 ...

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  20. Give the formula and describe the structure of a noble gas which is is...

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