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Explain briefly how +2 state become more...

Explain briefly how `+2` state become more and stable in the first half of the first row transition elements with increasing atomic number?

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The sum `IE_1+IE_2` increase. As a result, the standard reduction potentials `(E^(ɵ))` become less and less negative. Hence, the tendency to form `M^(2+)` ion decrease. The greater Stability of `+2` state for Mn is due to half-filled d-subshell `(d^5)` that for zinc is due to completely filled d-subshell `(d^(10))` and that for nickel is due to highest (negative) enthalpy of hydration.
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CENGAGE CHEMISTRY-APPENDIX INORGANIC VOLUME 2-Exercises
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  4. To what extent do the electronic configurations, decide the stability ...

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  5. What may be the stable oxidation state of the transition elements with...

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  7. What is lanthanoid contraction? What are the consequences of lanthanol...

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  8. What are the characteristics of th transition elements and why are the...

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  9. In What way is the electronic configuration of the transition elements...

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  10. What are the different oxidation states exhibited by the lanthanoids?

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  11. What are interstitial compounds? Why are such compounds well known for...

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  12. How is the variability in oxidation states fo transition metals differ...

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  13. Describe the oxidising action of potassium dichromate and write the io...

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  14. For (M^(2+))/(M) and (M^(3+))/(M^(2+)) systems the E^(ɵ) values for so...

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  15. Predict which of the followingwill be coloured in aqueous solution? T...

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  16. Compare the chemistry of actinoids with that of the lanthanoids with s...

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  17. How would you account for the following. (i). Of the d^4 species. Cr...

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  18. What is meant by 'disproportionation'? Give two examples of disproport...

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  19. Which metal in the first series of transition metals exhibits+1 oxidat...

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  20. Calculate the number of unpaired electrons in the following gaseous io...

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