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The chemistry of the actinoid elements i...

The chemistry of the actinoid elements is not so smooth as that of the lanthanoid. Justify this statement by giving some example from the oxidation state of these elements

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Lanthanoids shw limited number of oxidation state e.g., `+2+3` and `+4` (out of which `+3` is most common). This is because of large energy gap between `4f,5d` and `6s` subshells. The dominant state of actinoids is also `+3` but they show a number of other oxidation states also,
e.g., uranium `(Z=92)` and plutonium `(Z=94)`, Show `+3`,`+4,+5` and `+6`, neptunium `(Z=94)` shows `+3,+4,+5` and `+7`, etc. This is due to small energy difference between 5f, 6d and 7s subshells of the actinoids.
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CENGAGE CHEMISTRY-APPENDIX INORGANIC VOLUME 2-Exercises
  1. What are alloys? Name an important alloy which contains some of the la...

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  2. What are inner transition elements? Decide which of the following atom...

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  3. The chemistry of the actinoid elements is not so smooth as that of the...

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  4. Which is the last element in the series of the actinods? Write the ele...

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  5. Use Hund's rule to derive the electronic configuration of Ce^(3+) ion,...

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  6. Name the member of the lanthanoids series which exhibit+4 oxidation st...

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  7. Compare the chemistry of actinoids with that of the lanthanoids with s...

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  8. Write the electronic configuration of the elements with the atomic num...

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  9. Compare the general characteristics of the first series of the transit...

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  10. Write doen the number of 3d electrons in each of the following ions: T...

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  11. Comment on the statement that elements of the first transition series ...

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  12. What can be inferred from the magnetic moment values of the following ...

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  13. Which one of the following postulates of Werner's theory is incorrect ...

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  14. FeSO4 solution mixed with (NH4)2SO4 solution is 1:1 molar ratio gives ...

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  15. Explain with two examples each of the following coordination entity, l...

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  16. What is meant by unidentate and ambidentate ligands? Give two examples...

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  17. Specify the oxidation numbers of the metals in the following coordinat...

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  18. Using IUPAC norms write the fomulas for the following (i). Tetrahydr...

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  19. Using IUPAC norms write the systematic names of the following: (i). ...

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  20. How many geometrical isomers are possible in the following corrdinatio...

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