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Specify the oxidation numbers of the met...

Specify the oxidation numbers of the metals in the following coordination entities:
(i). `[Co(H_2O)(CN)(en)_2]^(2+)`
(ii). `[CoBr_2(en)_2]^(o+)`
(iii). `[PtCl_4]^(2-)` ltbtgt (iv). `K_3[Fe(CN)_6]`
(v). `[Cr(NH_3)_3Cl_3]`

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(i). `[overset(x)(C)o(overset(0)(H_2O)(Coverset(-1)(N))(eoverset(0)(n))_2]^(2+)`
`impliesx+(0)+(-1)+(0)=+2`
(ii). `[overset(x-1)(PtCl_4]^(2-)]`
`impliesx+(-1)xx4=-2,becausex=+2`
(iii). `[overset(x)(C)r(Noverset(0)(H)_3)_3(Coverset(-1)(l)_3)]`
`impliesx+(0)xx(3)+(-1)xx(3)=0,impliesx=+3`
(iv). `[(overset(x)(C)0overset(-1)(B)r_2)(eoverset(0)(n))_2]^(o+)`
`impliesx+(-1)xx(2)+(0)xx(2)=+1impliesx=+3`
(v). `overset(+1xx3)(K_3)[Fe(Coverset(-1)(N))_6]^(-3)`
`implies3(+1)xx x +(-1)(6)=0impliesx=+3`
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Specify the oxidation numbers of metals in the following co-ordination entites : (a) [Co(H_(2)O)(CN)(en_(2))]^(2+) (b) [PtCI_(4)]^(2-) (c) [Cr(NH_(3))_(3)CI_(3)] (D) [CoBr_(2)(en)_(2)]^(+) (e) K_(3)[Fe(CN)_(6)] .

What is the oxidation number of the metal atom in the following ions? (i) [Fe(CN)_(6)]^(3) ,(ii) MnO_(4), (iii) [Cr(H_(2)O)_(6)]^(3^(+)

Give the oxidation states of the central matal in the following complex compounds , (i) K_(3)[Fe(CN)_(6)] (ii) [PtCl_(4)]^(2-) (iii) [Co(en)_(2)Cl_(2)]^(+) .

Write the IUPAC names for the following coordination compounds: (i). [Co(NH_3)_6]Cl_3 (ii). [Co(NH_3)_5Cl]Cl_2 (iii). K_2[Fe(CN)_6] (iv). K_3[Fe(C_2O_4)_3] (v). K_2[PdCl_4] (vi). [Pt(NH_3)_2Cl(NH_2CH_3)]Cl

Give the names of the followng complexes according to IUPAC system (i) [CoCl_2(en)_2]Cl (ii) K_3{Fe(CN)_6} .

Draw the structures of optical isomers of: (i). [Cr(C_2O_4)_3]^(3-) (ii). [PtCl_2(en)_2]^(2+) (iii). [Cr(NH_3)_2Cl_2(en)]^(o+)

CENGAGE CHEMISTRY-APPENDIX INORGANIC VOLUME 2-Exercises
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  2. What is meant by unidentate and ambidentate ligands? Give two examples...

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  3. Specify the oxidation numbers of the metals in the following coordinat...

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  4. Using IUPAC norms write the fomulas for the following (i). Tetrahydr...

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  5. Using IUPAC norms write the systematic names of the following: (i). ...

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  6. How many geometrical isomers are possible in the following corrdinatio...

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  7. Draw the structures of optical isomers of: (i). [Cr(C2O4)3]^(3-) (...

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  8. Draw the structures of optical isomers of: (i). [Cr(C2O4)3]^(3-) (...

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  9. Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how man...

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  10. Aqueous copper sulphate solution (blue in colour) gives: (i). A gree...

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  11. What is the coordination entity formed when excess of aqueous KCN is a...

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  12. Discuss the nature of bonding in the following coordination entities o...

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  13. What is crystal field splitting energy? How does the magnitude of tria...

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  14. What is spectrochemical series?

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  15. What is crystal field splitting energy? How does the magnitude of tria...

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  16. [Cr(NH3)6]^(3+) is paramagnetic while [Ni(CN)4]^(2-) is diamagnetic. E...

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  17. Assertion: A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution o...

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  18. [Fe(H2O)6]^(3+) is strongly paramagnetic whereas [Fe(CN)6]^(3-) is wea...

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  19. BONDING IN METAL CARBONYLS

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  20. Give the oxidation state, d-orbitals occupation and coordination numbe...

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