Home
Class 11
CHEMISTRY
Give the order of (a) nucleophilicity (b...

Give the order of `(a)` nucleophilicity `(b)` basic character, and `(c)` fugacity of the following :
(i) `F^(Ө)`
(ii) `Cl^(Ө)`
(iii) `Br^(Ө)`
(iv) `I^(Ө)`.

Text Solution

Verified by Experts

(a) and (c) : `(iv) gt (iii) gt (ii) gt (i) (I^(Ө) gt Br^(Ө) gt Cl^(Ө) gt F^(Ө))` , `(b)` reverse.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Subjective|19 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Comprehension|36 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Analytical and Descriptive|6 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Chemical Equilibrium|72 Videos
  • P-BLOCK GROUP 13 - BORON FAMILY

    CENGAGE CHEMISTRY|Exercise Exercise Archives (Subjecive)|9 Videos

Similar Questions

Explore conceptually related problems

The decreasing basic character of the following is : (I) Ph O^(Ө) (II) CH_3 S^(Ө) (III) overset (Ө) O H (IV) MeO^(Ө) .

The decreasing nucleophilicity of the following is : (I) CH_3 S^(Ө) (II) CH_3 O^(Ө) (III) overset (Ө) O H (IV) EtO^(Ө) .

Predict the order of nucleophicity of X^(Ө) in the following reaction : .

The decreasing order of nucleophilicities of the following is : (I) Br^(Ө) (II) MeO^(Ө) (III) Me_2 N^(Ө) (IV) Me_3 C^(Ө) .

The decreasing order of the basic character of the following is : (I) F^(Ө) (II) NO_3^(Ө) (III) H_2 O (IV) CH_3 OH .

The decreasing order of nucleophilicities of the following is : (I) H_2 O (II) EtOH (III) MeCOO^(Ө) (IV) overset (Ө) O H (V) EtO^(Ө) .

The decreasing order of + I effect of the following is : (I) - O^(Ө) (II) Me- (III) Et- (IV) Me_2CH- (V) Me_3 C- .

The order of stability of the following carbanion is (I) CH_(3)overset(Ө)CH_(2)

CENGAGE CHEMISTRY-ORGANIC REACTION MECHANISM-Solved Example
  1. Give the order of reactivity towards aqueous HCOOH of the following. ...

    Text Solution

    |

  2. Give the order of hydrolysis in SN^1 process for the following : ...

    Text Solution

    |

  3. Give the order of (a) nucleophilicity (b) basic character, and (c) fug...

    Text Solution

    |

  4. Give the most reactive substrate in each of the following pair with ov...

    Text Solution

    |

  5. Outline the synthesis of following compounds from suitable nucleophile...

    Text Solution

    |

  6. Give a suitable mechanism for the following : .

    Text Solution

    |

  7. Predict the order of reactivity of the following halides with (a) NaI ...

    Text Solution

    |

  8. Explain : (a)ClCH2OCH3 (chloromethyl methyl ether) undergoes SN^1 re...

    Text Solution

    |

  9. Write the products of the following SN reactions. .

    Text Solution

    |

  10. Complete the following reaction

    Text Solution

    |

  11. Bromobenzene can be dehydrobrominated to benzyne by three possible rou...

    Text Solution

    |

  12. Classify the following reactions as addition, elimination, substitutio...

    Text Solution

    |

  13. From the following elimination reactions, predict which one is Hofman...

    Text Solution

    |

  14. Which one is more reactive towards acidcatalysed hydration ? Predict t...

    Text Solution

    |

  15. Which one hydrolyses at a faster rate by SN^1 mechanism ? .

    Text Solution

    |

  16. Explain :

    Text Solution

    |

  17. What are the products of addition of D2 to trans-2-pentene.

    Text Solution

    |

  18. Meso-2,3-dibromobutane reacts with iodide ion more rapidly than does (...

    Text Solution

    |

  19. Mustard gas (ClCH2CH2)2-S hydrolysed by water to Cl(CH2)2 S(Ch2)2 OH m...

    Text Solution

    |

  20. Give the product, indicating stereo-chemistry of cyclohexene with : ...

    Text Solution

    |