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In which of the reactions, there is a mi...

In which of the reactions, there is a migration of alkyl group to carbene `(ddot C H_2)`, i.e., rearrangement occurs ?

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
A, B, C

The reaction (a) is Arndt-Eistert reaction.
The reactions (b) and (c) are Wolff rearrangement reactions.
The reaction (d) is Hofmann bromamide rearrangement reaction.
It involves acylnitrene intermediate and migration if alkyl group to `N` atom occurs to form `(R - N = C = O)`
(a,b,c) involves the formation of
intermediate in which `R` migrates to carbene to form `R-CH=C=O`.
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