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Which of the following statements are co...

Which of the following statements are correct?

A

(a) `DeltaH_c^@` of cis-pent-2-ene is greater than trans-pent-2-ene

B

(b) `DeltaH_c^@` of hex-1-ene is greater than trans-hex-2-ene

C

(c) `DeltaH_c^@` of 2,5-dimethyl hexane is greater than octane

D

(d) `DeltaH_c^@` of 2-methyl-pent-2-ene is greater than trans-hex-2-ene
`DeltaH_c^@=`Heat of combusion

Text Solution

Verified by Experts

The correct Answer is:
A, B, D

Lower the `DeltaH_C^@`, more stable is the compound, So trans alkane is more stable than cs alkene. The statement (c) is wrong because 2,5-dimethyl hexane is more stalbe (due to smaller surface area) than octane. Therefore, `DeltaH_C^@` of 2, 5-dimethyl hexane should be lower than octane.
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