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Compound (A) reacts with [Cu(NH3)2]^(+) ...

Compound (A) reacts with `[Cu(NH_3)_2]^(+)` and Tollens reagent, but after with alc: KOH it does not give the above test. Compound (A) is:

A

(a) `Me--=-Me`

B

(b) `Me--=-H`

C

D

(d) `Ph--=-H`

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The correct Answer is:
C

Terminal alkyne containing four or more C atoms on reaction with alk. KOH isomerises to internal alkynes, which do not give all the tests mentioned. Although (b) and (d) are also terminal alkynes, they do not have sufficient C atoms to be converted to internal alkynes. So the answer is (c).
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CENGAGE CHEMISTRY-ALKYNES-Exercises (Multiple Correct Answers Type)
  1. In the following sequence of reactions, Which of the statements a...

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  2. Acetylene is thermodynamically unstable and readily explodes, therefor...

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  3. Which of the statements are correct for alkyne with molecular formula ...

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  4. For the conversion of alkyne to cis-alkene, H2+ Lindlar's catalyst is ...

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  5. i. Me--=-Hunderset((ii)H2O2//overset(Ө)OH)overset((i) Sia2BH)rarrA i...

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  6. Which of the following statements are correct?

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  7. Which of the following statement(s) is/are correct:

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  8. Compound (B) is same when (A) is:

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  9. Which of the statements are correct? R--=-R^'underset(+EtOH)overset(...

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  10. Which of the statements are correct? R--=-Runderset(Catalyst)overset...

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  11. Hydroboration oxidation and acid hydration will yield the same product...

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  12. C4H6underset(1 mol)overset(H2+Pt)rarrC4H8overset(O3//H2O)rarr Acedic a...

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  13. All reagents, [Cu(NH3)2]^(o+), [Ag(NH3)2]^(o+), CH3MgBr, and NaNH2 r...

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  14. Compound (A) does not react with Tollens or Grignard reagent, but afte...

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  15. Compound (A) reacts with [Cu(NH3)2]^(+) and Tollens reagent, but after...

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  16. Which of the statements are correct?

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  17. Reagents used in conversion from (A) to (B) are:

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  18. Which gas is in an antidote of Lewisite (a poisonous gas used in World...

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  19. Which statements are correct:

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  20. Which statements are correct for reagents A, B, C, and D?

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