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Ethylmercaptan is prepared by the reacti...

Ethylmercaptan is prepared by the reaction of the following, followed by hydrolysis :

A

`C_2 H_5 MgBr + SO_2`

B

`C_2 H_5 Mg Br + S`

C

`C_2 H_5 MgBr + CS_2`

D

`C_2 H_5 Mg Br + H_2 S`.

Text Solution

Verified by Experts

The correct Answer is:
B

(b) `C_2 H_5 Mg Br + S underset (H_3 O^(oplus))rarr C_2 H_5- SH`.
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CENGAGE CHEMISTRY-GRIGNARD REAGENTS AND ORGANOMETALLIC REAGENTS-Exercises (Single Correct)
  1. .

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  2. .

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  3. Ethylmercaptan is prepared by the reaction of the following, followed ...

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  4. Methyl oxirane on reaction with CH3 MgBr, followed by hydrolysis, give...

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  5. Benzonitrile on reaction with C2 H5 MgBr, followed by hydrolysis, give...

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  6. Acetoisonitrile on reaction with C2 H5 MgBr followed by hydrolysis, gi...

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  7. .

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  8. Propane dithioic acid is prepared by the reaction of the following, fo...

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  9. Propylsulphinic acid is prepared by the reaction of the following, fol...

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  10. .

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  11. Ethanoic propanoic anhydride on reaction with excess of MeMgBr gives t...

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  12. Reactivity of MeMgBr with the following in the decreasing order is : ...

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  13. Product. The major product is :

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  14. Reactivity of with the following G.R in the decreasing order is : (...

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  15. .

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  16. Reactivity of EtMgBr with the following in the decreasing order is : ...

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  17. Reactivity of PhMgBr with the following in the decreasing order is : ...

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  18. Reactivity of PrMgBr with the following in the decreasing order is : ...

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  19. Reactivity of HCHO with the following G.R in the decreasing order is :...

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  20. Which of the following 3^@ alcohols does propyl ester give during reac...

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