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Explain how does the (---OH) group attac...

Explain how does the `(---OH)` group attached to a carbon of benzene ring activate it towards electophililc substitution.

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Phenol may be regarded as a resonance hybrid of structures, I-V as shown in Section `12.10` (b). As a result of `+R` effect of the `(OH)` group, the electron density in the benzene ring increases, thereby facilitating the attack by an electophile. In other words, the presence of `(OH)` group activates the benzene ring towards electrophilic substitution reactions. Further, since the electron density is relatively higher at the two o- and p-position, therefore, electrophilic substitution occurs mainly at o-and p-position.
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CENGAGE CHEMISTRY-ALCOHOL,PHENOL AND ETHERS-Exercises Concept Application
  1. Give two reactions that show the acidic nature of phennol. Compare the...

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  2. Explain why is ortho-nitrophenol more acidic than ortho-methoxyphenol ...

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  3. Explain how does the (---OH) group attached to a carbon of benzene rin...

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  4. Give the equations of the following reactions: i. Oxidation of prop...

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  5. Explain the following with an example: i. Kolbe's reaction ii. R...

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  6. Write the mechanism of hydration of ethene to yield ethanol.

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  7. How are the following conversions carried out ? i. Propene rarr Pro...

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  8. Name the reagents used in the following reactions: i. Oxidation of ...

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  9. Given reason for the higher boiling point of ethanol in comparison to ...

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  10. Give the IUPAC names of the following ethers: C(2)H(5)OCH(2)--overse...

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  11. Write the names of reagents and equations for the preparation of follo...

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  12. Illustrate with examples the limitations of Williamson's synthesis for...

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  13. How is 1-propoxyproapane synthesised from propan-1-ol ? Write mechanis...

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  14. Preparation of ethers by acid dehydration of secondary or tetiary alco...

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  15. Write the equation of the reaction of hydrogen iodide with : (i) 1-p...

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  16. Explain the fact that in aryl ethers, (i) the alkoxy group activates t...

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  17. Write the mechanism of the reaction of Hiwith methoxymethane.

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  18. Write the equations of the following reactions: i. Friedel-Crafts r...

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  19. Show how would you synthesisse the following alcohols form approprite ...

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  20. when 3-methylbutan-2-ol is treated with HBr, the following reaction ta...

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