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The compounds (D) and (E ) are:...


The compounds (D) and (E ) are:

A

Enantiomers

B

Diastereomers

C

Geometrical isomers

D

Positional isomers

Text Solution

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The correct Answer is:
A

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An organic compound (A) C_(5)H_(9) Br which readily decolourises bromine water and KMnO_(4) solution gives (B), C_(5)H_(11)Br on treatment with Sn//HCI . The reaction of (A) with NaNH_(2) produces (C) with evolution of ammonia (C) neither reacts with sodium nor forms any metal acetylide but reacts with Lindlar catalyst to give (D) and on reaction with Na//liq . NH_(3) produces (E) .Both the compounds (D) and (E) are isomeric. Give structures of (A) to (E) with proper reasoning.

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The compounds (D) and (E) respectively are:

The compound (D) is:

The compound (D) is:

The compound (D) is:

The compound (D) is:

(a) On bolining a minerak (A) with NaCO_(3) solution, a white precipirtate (B) is formed. (b) The precipitate is fitered and the filtrate contains two conpounds ( C) and (D) . The componds ( C) is removed by crystallisation and when CO_(2) is passed through the mother liquor left, (D) changes to ( C) . ( c) On strongly heating ( C) , two compounds (D) and ( E) are formed. (d) (E) on heating with cobalt oxide provides blue-coloured substance (F) . Identify (A) to (F) and give chemical reaction for (a) to (d) .

The compounds (E) is: