Home
Class 12
CHEMISTRY
The decreasing order of acidic character...

The decreasing order of acidic character of the following is:
(I) `Ph-overset(O)overset(||)(C)-NH_(2)` (II) (III) `PhNH_(2)`

A

`II gt I gt III`

B

`III gt I gt II`

C

`II gt III gt I`

D

`I gt III gt II`

Text Solution

Verified by Experts

The correct Answer is:
A

Due to two `bar e`-withdraw `(C=O)` groups in (II), it is more acidic than (I) (one EW `(C=O)` group). Moreover, (II) is much more resonance stabilised than (I).
(II)
(I)
Promotional Banner

Topper's Solved these Questions

  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY|Exercise Exercises Assertion-Reasoning|10 Videos
  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY|Exercise Archives Single Correct|14 Videos
  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY|Exercise Exercises Multiple Correct|35 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY|Exercise Archives Subjective|29 Videos

Similar Questions

Explore conceptually related problems

The decreasing order of acidic character of the following is: (I) (II) (III) (IV)

The decreasing order of stabilities of the following carbanions is : (I) Ph_3 overset (Ӫ)C (II) Ph_2 overset (Ӫ) CH_2 (III) Ph overset (Ӫ) C H_2 .

The decreasing order of -I effect of the following is I. -overset(o+)NH_(3) . II. -NO_(2) III. -CN IV. -COOH

The decreasing order of acidic character of the following is : (I) p-Nitrophenol (II) o-Nitrophenol (III) m-Nitrophenol (IV) Phenol.

Give the decreasing order of acidities of : (a) (I) H_(3)C-overset(O)overset(||)(C)-OMe (II) H_3 C - CH = O (III) H_(3)C-underset(O^(Theta))underset(|)overset(o+)(N)=O and explain. (b) Give the factors that affect relative basicities.

The decreasing basic character of the following is : (I) Ph O^(Ө) (II) CH_3 S^(Ө) (III) overset (Ө) O H (IV) MeO^(Ө) .

The increasing order of K _(b) for the following compounds will be: H _(2) N- overset(NH) overset(||) underset(I)(C)-NH_(2), CH_(3) -overset(NH) overset(||)underset(II) (C)-NH_(2), underset(III)(CH_(2))-NH_(2)

Arrange the following compound is decreasing order of macheophillic addection reation (I) CH_(3)-overset(O)overset(||)(C)-CH_(3) (II) CH_(3)-overset(O)overset(||)(C)-CI (III) CH_(3)-overset(O)overset(||)(C)-NH_(2) (Iv) CH_(3)-overset(O)overset(||)(C)-OH (V) CH_(3)-overset(O)overset(||)(C)-O-overset(O)overset(||)(C)-CH_(3)

CENGAGE CHEMISTRY-ALCOHOL,PHENOL AND ETHERS-Exercises Single Correct
  1. The decreasing order of acidic character of the following is: (I) Et...

    Text Solution

    |

  2. The decreasing order of acidic character of the following is: (I) ...

    Text Solution

    |

  3. The decreasing order of acidic character of the following is: (I) Ph...

    Text Solution

    |

  4. Consider the following reaction and identify (B).

    Text Solution

    |

  5. Give the decreasing order of the reaction rates of the following benzy...

    Text Solution

    |

  6. Give the decreasing order of reactivity of the following compounds wit...

    Text Solution

    |

  7. The product (B) is:

    Text Solution

    |

  8. The product (B) is:

    Text Solution

    |

  9. Which of the following is the best synthesis of the ether (A) shown be...

    Text Solution

    |

  10. The compound (C ) is:

    Text Solution

    |

  11. The product (B) is:

    Text Solution

    |

  12. Phenol reacts with PCI(5), the main product is:

    Text Solution

    |

  13. Phenol overset(Aerial)underset(oxid)rarr coloured. This is due to the ...

    Text Solution

    |

  14. The compound (C ) is:

    Text Solution

    |

  15. The product (B) is:

    Text Solution

    |

  16. Which is the best method the conversion of (A) pentan-2-ol to 3-bromop...

    Text Solution

    |

  17. Which statement is correct for the conversion of ROH to RX by regents ...

    Text Solution

    |

  18. Which of the following statements is wrong about the following reactio...

    Text Solution

    |

  19. Consider the reaction C(3)H(7)-OH+Et(3)O^(o+)BF(4)^(-)rarr C(3)H(7)-...

    Text Solution

    |

  20. Consider the reaction: C(2)H(5)O^(-)+ Dimethyl sulphate (Me-O-overset...

    Text Solution

    |