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Four isomeric optically active compounds...

Four isomeric optically active compounds `overset (NaHCO_3) rarr CO_2 (g) (A, B , C, D) (C_4 H_8 O_3)`
Compound `(A) overset (LAH) rarr ( E)` (Archiral compound)
Compound `(B) overset (KMnO_4) underset (or CrO_3) rarr` Inert to oxidation.
Compound `( C) underset (NaOI//H_3 O^(oplus)) rarr CHI_3 (Yellow ppt.) + Compound (F)`.
Compound `( C)` is :

A

`(I)`

B

`(II)`

C

`(III)`

D

`(IV)`

Text Solution

Verified by Experts

The correct Answer is:
B

(b) (i) From the structures gives in the problem, `(A)` is `(I)`. Since with `LAH` it would give achiral compound `( E)`.

(ii) `(B)` id `(IV)`, since ethers are inert to oxidation.
(iii) Iosoform test is shown by `(II)`, so `(C)` is `(II)`.
(iv) .
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CENGAGE CHEMISTRY-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Linked Comprehension)
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  3. Four isomeric optically active compounds overset (NaHCO3) rarr CO2 (g)...

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  4. Four isomeric optically active compounds overset (NaHCO3) rarr CO2 (g)...

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  5. Four isomeric optically active compounds overset (NaHCO3) rarr CO2 (g)...

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  6. (i) Carboxylic acid (ii) Compound (D) is prepard by carbonation(Mg/...

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  7. (i) Carboxylic acid (ii) Compound (D) is prepard by carbonation(Mg/...

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  8. (i) Carboxylic acid (ii) Compound (D) is prepard by carbonation(Mg/...

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  9. (i) Carboxylic acid (ii) Compound (D) is prepard by carbonation(Mg/...

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  10. Compound (B) is :

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  11. Compound ( C) is :

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  12. Compound ( E) is :

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  13. Compound (F) is :

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  14. Compound (F) is used as an artificial sweetner and is known as sacchar...

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  15. Compound (B) is :

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  16. In the formation of ( C) from (A) and (B), which statements (s) is //a...

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  17. Which statement (s) is //are correct about the formation of (D) ?

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  18. Which statements is//are correct about the formation of ( E) from (D) ...

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  19. Product ( E) is :

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  20. Three isomeric tetracarboxylic acids (I),(II), and (III) are given. ...

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