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(I) is more acidic than The negative c...

(I) is more acidic than
The negative charge of the conjugate base of `(II)` cannot be delocalised through the benzene ring.

A

If both `(A)` are `( R)` are true and `( R)` is the correct explanation of `(A)`.

B

If both `(A)` and `( R)` are true but `( R)` is not the correct explanation of `(A)`.

C

If `(A)` is true but `( R)` is false.

D

If `(A)` is false but `( R)` is true.

Text Solution

Verified by Experts

The correct Answer is:
D

`PhCOOH (II)` is more acidic than `(I)` due to `(-I)` and `(+R)` effects of `(Ph)` group. `(I)` is less acidic due to `(+I)` effect of its `R^, s`of the sides of the ring, so `(A)` is false.

can delocalise to `(C = O)` group but not with the benzene ring because `O^(Ө)` is not in conjugation with `(C = C)` bond of benzene ring.
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