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The aqueous solution of a nitrogen and c...

The aqueous solution of a nitrogen and chlorine containing organic compound `(A)` is acidic to litmus. `(A)` on treatment with aqueous `NaOH`gives a compound `(B)` on treatement with `C_(6)H_(5)SO_(2)CI` in the presence of `NaOH` gives an insoluble product `(C)` `C_(13)H_(13)NO_(2)S`. give the structures of `(A)` and `(B)`.

Text Solution

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`(A)rArrPh-underset(CH_(3))underset(|)overset(o+)NH_(2)]CI^(Theta) (B) rArrPh-NH-CH_(3)`
`C rArrPh-underset(CH_(3))underset(|)N-overset(O)overset(||)underset(O)underset(||)(S)-Ph ("Insoluble in" NaOH)`
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