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An amino acid reacts with 10ml 0.05MNaOH...

An amino acid reacts with `10ml 0.05MNaOH` and the final solution has`pH=2.30` When`20ml` of these base is added in the resulting solution.The `pH` become`9.7`.Identify the amino acid and calculate the isoelectric point of the amino acid.This amino acid is prepared by the reaction of compound `(X)`with `NH_(3)`and further hydrolysis with `HCN`compound `(X)` is less `C`atom containing compound that gives postitive iodoform test and positive Fehling's solution test.
Compound (X) is:

A

`CH_(3)CHO`

B

`CH_(3)CH_(2)CHO`

C

D

Text Solution

Verified by Experts

Compound (X) is `CH_(3)-overset(O)overset(||)(C)-H`
` (##KSV_CHM_ORG_P2_C15_E01_041_S01.png" width="80%">
When partial neutralisation of alanine occurs .
Then, `pH =pK_(a) +log [("salt")/("acid")]`
`["salt"] = ["acid"]`
`pH_(1) = pK_(a_(1))` and `pH_(2) =pK_(a_(2))`
`:. pH = (pK_(a_(1))+pK_(a_(2)))/(2)=(9.7+2.3)/(2)=(12.0)/(2)=6.0`
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An amino acid reacts with 10ml 0.05MNaOH and the final solution has pH=2.30 When 20ml of these base is added in the resulting solution.The pH become 9.7 .Identify the amino acid and calculate the isoelectric point of the amino acid.This amino acid is prepared by the reaction of compound (X) with NH_(3) and further hydrolysis with HCN compound (X) is less C atom containing compound that gives postitive iodoform test and positive Fehling's solution test. Amino acid is:

An amino acid reacts with 10ml 0.05MNaOH and the final solution has pH=2.30 When 20ml of these base is added in the resulting solution.The pH become 9.7 .Identify the amino acid and calculate the isoelectric point of the amino acid.This amino acid is prepared by the reaction of compound (X) with NH_(3) and further hydrolysis with HCN compound (X) is less C atom containing compound that gives postitive iodoform test and positive Fehling's solution test. Isoelectric point of the amino acid is:

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CENGAGE CHEMISTRY-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP-Exercises Linked Comprehension
  1. (i) (ii) Compound(D)is:

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  2. An amino acid reacts with 10ml 0.05MNaOH and the final solution haspH=...

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  3. An amino acid reacts with 10ml 0.05MNaOH and the final solution haspH=...

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  4. An amino acid reacts with 10ml 0.05MNaOH and the final solution haspH=...

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  5. Compound(A)is:

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  6. Compound (B) is:

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  7. Compound (C ) is:

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  8. Compound(D )is:

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  9. Compound(E )is:

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  10. [A],[B],[C],[D],[E],[F],and [G] are amines,each of which forms a hydro...

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  11. [A],[B],[C],[D],[E],[F],and [G] are amines,each of which forms a hydro...

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  12. [A],[B],[C],[D],[E],[F],and [G] are amines,each of which forms a hydro...

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  13. [A],[B],[C],[D],[E],[F],and [G] are amines,each of which forms a hydro...

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  14. [A],[b],[C],[D],[E],[F],and[G] are amines,each of which forms a hydroc...

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  15. [A],[b],[C],[D],[E],[F],and[G] are amines,each of which forms a hydroc...

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  16. [A],[b],[C],[D],[E],[F],and[G] are amines,each of which forms a hydroc...

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  17. A substance(X) contains 41.37% C,6.89% H.0.166gm of (X) gaveNH(3) whic...

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  18. A substance(X) contains 41.37% C,6.89% H.0.166gm of (X) gaveNH(3) whic...

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  19. A substance(X) contains 41.37% C,6.89% H.0.166gm of (X) gaveNH(3) whic...

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  20. A substance(X) contains 41.37% C,6.89% H.0.166gm of (X) gaveNH(3) whic...

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