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Compound(E )is:...

Compound`(E )`is:

A

`CH_(3)-overset(OCH_(3))overset(|)underset(CH_(3))underset(|)(C)-CH_(2)-CH_(2)-overset(CH_(3))overset(|)(N)-N=O`

B

`CH_(3)-underset(CH_(3))underset(|)(CH)-underset(OCH_(3))underset(|)(CH)-CH_(2)-overset(CH_(3))overset(|)(N)-N=O`

C

D

`CH_(3)-underset(CH_(3))underset(|)(CH)-CH_(2)-underset(OCH_(3))underset(|)(CH)-overset(CH_(3))overset(|)(N)-N=O`

Text Solution

Verified by Experts


i. 2-Methoxy -2-methyl propane is obtained by the oxidation of (D) followed by decarbozylation and thue (D) is
`CH_(3)-overset(OCH_(3))overset(|)underset(CH_(3))underset(|)(C)-CH_(2)CH_(2)OH`
ii. (D) is formed by the action of ` HNO_2` on (B ) thus (B ) is
`CH_(3)-overset(OCH_(3))overset(|)underset(CH_(3))underset(|)(C)-CH_(2)CH_(2)NH_(2)`
iii. (B) is formed by the acion of `NH_3` over (A) , a bromodecivatiove .
`(A) rArr CH_(3)-overset(OCH_(3))overset(|)underset(CH_(3))underset(|)(C)-CH_(2)CH_(2)Br`
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