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For a chemical reaction rate law is, rat...

For a chemical reaction rate law is, rate `= k{A]^(2)[B]`. If [A] is doubled at constant [B], the rate of reaction

A

increases by a factor of 8

B

increases by a factor of 4

C

incr-eases by a factor of 3

D

increases by a factor of 2

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The correct Answer is:
To solve the problem, we need to analyze how the rate of reaction changes when the concentration of reactant A is doubled while keeping the concentration of reactant B constant. ### Step-by-Step Solution: 1. **Understand the Rate Law Expression**: The rate law is given as: \[ \text{Rate} = k[A]^2[B] \] Here, \(k\) is the rate constant, \([A]\) is the concentration of reactant A, and \([B]\) is the concentration of reactant B. 2. **Define Initial Rate**: Let the initial concentration of A be \([A]\) and the concentration of B be \([B]\). The initial rate of the reaction can be expressed as: \[ R = k[A]^2[B] \] 3. **Change the Concentration of A**: If the concentration of A is doubled, then the new concentration of A becomes \(2[A]\). The concentration of B remains constant at \([B]\). 4. **Calculate the New Rate**: Substitute \(2[A]\) into the rate law to find the new rate \(R'\): \[ R' = k(2[A])^2[B] \] 5. **Simplify the Expression**: Now, simplify the expression for \(R'\): \[ R' = k(4[A]^2)[B] = 4k[A]^2[B] \] 6. **Relate New Rate to Initial Rate**: Since \(R = k[A]^2[B]\), we can substitute this into the equation for \(R'\): \[ R' = 4R \] 7. **Conclusion**: Therefore, when the concentration of A is doubled, the rate of reaction increases by a factor of 4. ### Final Answer: The rate of reaction increases by a factor of 4.

To solve the problem, we need to analyze how the rate of reaction changes when the concentration of reactant A is doubled while keeping the concentration of reactant B constant. ### Step-by-Step Solution: 1. **Understand the Rate Law Expression**: The rate law is given as: \[ \text{Rate} = k[A]^2[B] ...
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