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Which of the following sets of solutio...

Which of the following sets of solutions of urea
.

A

9. 1 `gL^(-1)` urea and 6.0 `gL^(-1)`sucrose

B

3.0 `gL^(-1)` 1 urea and 3.0 `gL^(-1)` sucrose

C

6.0 `gL^(-1)` urea and 9.0 `gL^(-1)` sucrose

D

3.0 `gL^(-1)` urea and 17.1 `gL^(-1)` sucrose

Text Solution

Verified by Experts

The correct Answer is:
D

Formula for osmotic pressure, `pi = CRT`
Considering the set given in option (d), i.e., `3.0 gL^(-1)` urea and `17.1 gL^(-1)` sucorse.
Given molecular mass of urea `60 g mol^(-1)` and molecular mass of sucrose `342 g mol^(-1)` For urea.
Conc. `C = (3)/(60) = (1)/(20)`
Osmetic pressure `pi_(1) = (1)/(20) xx R xx T`
For sucrose conc. `C = (17.1)/(342) = (1)/(20)`
`:.` Osmotic pressure, `pi_(2) = (1)/(20) RT`
Thus set of solution of urea and sucrose given in option (d) is isotonic.
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