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Kekule Structure

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Calculate the resonance enegry of toulene (use Kekule structure form the following data C_(7)H_(8)(l) +9O_(2)(g) rarr 7CO_(2)(g) +4H_(2)O(l)+ DeltaH, DeltaH^(Theta) =- 3910 kJ mol^(-1) C_(7)H_(8)(l) rarr C_(7)H_(8)(g), DeltaH^(Theta) = 38.1 kJ mol^(-1) Delta_(f)H^(Theta) (water) =- 285.8 kJ mol^(-1) Delta_(f)H^(Theta) [CO_(2)(g)] =- 393.5 kJ mol^(-1) Heat of atomisaiton of H_(2)(g) = 436.0 kJ mol^(-1) Heat of sulimation of C(g) = 715.0 kJ mol^(-1) Bond energies of C-H, C-C , and C=C are 413.0, 345.6 , and 610.0 kJ mol^(-1) .

Calculate the resonance energy of toluene (use Kekule structure from the following data C_(7)H_(8)(l) +9O_(2)(g) rarr 7CO_(2)(g) +4H_(2)O(l)+ DeltaH, DeltaH^(Theta) =- 3910 kJ mol^(-1) C_(7)H_(8)(l) rarr C_(7)H_(8)(g), DeltaH^(Theta) = 38.1 kJ mol^(-1) Delta_(f)H^(Theta) (water) =- 285.8 kJ mol^(-1) Delta_(f)H^(Theta) [CO_(2)(g)] =- 393.5 kJ mol^(-1) Heat of atomisation of H_(2)(g) = 436.0 kJ mol^(-1) Heat of sublimation of C(g) = 715.0 kJ mol^(-1) Bond energies of C-H, C-C , and C=C are 413.0, 345.6 , and 610.0 kJ mol^(-1) .

Discuss the Kekule's structure of benzene.

Write down the products of ozonolysis 1,2 -dimethylbenzene (o-xylene). How does the result support Kekule's structure for benzene ?

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