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For HCl solution at 25^(@)C, equivalent ...

For HCl solution at `25^(@)C,` equivalent conductance at infinite dilution, is `425 "ohm"​^(-1) cm​^(2) "equiv"^(-1)`​. The specific conductance of a solution of HCl is 0.3825 `"ohm​"^(-1) "​cm"​^(-1)`​. If the apparent degree of dissociation is 90% the normality of the solution is :-

A

0.90 N

B

1.0 N

C

10 N

D

1.2 N

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To find the normality of the HCl solution given the specific conductance, equivalent conductance at infinite dilution, and the degree of dissociation, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Given Values:** - Equivalent conductance at infinite dilution (λ∞) = 425 ohm⁻¹ cm² equiv⁻¹ - Specific conductance (κ) = 0.3825 ohm⁻¹ cm⁻¹ - Degree of dissociation (α) = 90% = 0.9 2. **Calculate the Equivalent Conductance at the Given Concentration:** The equivalent conductance (λ) at a particular concentration can be calculated using the formula: \[ \lambda = \alpha \times \lambda_{\infty} \] Substituting the values: \[ \lambda = 0.9 \times 425 \, \text{ohm}^{-1} \text{cm}^2 \text{equiv}^{-1} = 382.5 \, \text{ohm}^{-1} \text{cm}^2 \text{equiv}^{-1} \] 3. **Relate Specific Conductance to Normality:** The relationship between specific conductance (κ), equivalent conductance (λ), and normality (N) is given by: \[ \lambda = \frac{1000 \kappa}{N} \] Rearranging this formula to find normality (N): \[ N = \frac{1000 \kappa}{\lambda} \] 4. **Substituting the Known Values:** Now substitute κ and λ into the equation: \[ N = \frac{1000 \times 0.3825}{382.5} \] 5. **Calculating Normality:** \[ N = \frac{382.5}{382.5} = 1 \, \text{N} \] ### Final Answer: The normality of the HCl solution is **1 N**.

To find the normality of the HCl solution given the specific conductance, equivalent conductance at infinite dilution, and the degree of dissociation, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Given Values:** - Equivalent conductance at infinite dilution (λ∞) = 425 ohm⁻¹ cm² equiv⁻¹ - Specific conductance (κ) = 0.3825 ohm⁻¹ cm⁻¹ - Degree of dissociation (α) = 90% = 0.9 ...
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