35 when aniline reacts with oil of bitter almonds, (CH.CHO) condensation takes place and bencal derivative is formed. This is known as (1995) a Schiff's base Benedict's reagent Millon's hase d. Schiffsreagent c. Formic acide strength) d. Fluoroacetic acid bromoacetic acid (acid 18. For carbylamine reactio KOH and

When aniline reacts with oil of bitter almonds condensation takes place and benzal derivative is formed. This is known as:

When aniline reacts with oil of bitter almonds (C_(6)H_(5)CHO) condensation takes place and benzal derivative is formed This in knkown as .

When aniline reacts with oil of bitter almonds (C_(6)H_(5)CHO) condensation takes place and benzal derivative is formed This in knkown as .

.Which of the following changes occurs when trimethyl amine reacts with diborane A) Symmetric cleavage takes places B) Hybridization of boron remains same C) lonic product is formed D) Lewis acid - base reaction takes place

1,2-diols are oxidised to ketones or aldehydes by periodic acid HIO_(4) . Periodic acid reacts with dipol to form a cyclic intermeditate. The reaction takes places because iodine is in a highly positive oxidation state, so it readily accepts electrons. When the intermeidate breaks down, the bond between the two carbon bonded to the OH group break. Identify D.

Read the passage given below and answer the following questions: Reductive alkylation is the term applied to the process of introducing alkyl groups into ammonia or a primary or secondary amine by means of an aldehyde or ketone in the presence of a reducing agent. The present discussion is limited to those reductive alkylations in which the reducing agent is hydrogen and a catalyst or "nascent" hydrogen, usually from a metalacid combination, most of these reductive alkylations have been carried out with hydrogen and a catalyst. The principal variation excluded is that in which the reducing agent is formic acid or one of its derivatives, this modification is known as the Leuckart reaction. The process of reductive alkylation of ammonia consists in the addition of ammonia to a carbonyl compound and reduction of the addition compound or its dehydration product. The reaction usually is carried out in ethanol solution when the reduction is to be effected catalytically Since the primary amine is formed in the presence of the aldehyde it may react in the same way as ammonia, yielding an addition compound, a Schiff's base (RCH= NCH_(2)R) and finally, a secondary amine. Similarly, the primary amine may react with the imine, forming an addition product which also is reduced to a secondary amine Finally, the secondary amine may react with either the aldehyde or the imine to give products which are reduced to tertiary amines. Similar reactions may occur when the carbonyl compound employed is a ketone. (source: Emerson, W. S. (2011). The Preparation of Amines by Reductive Alkylation. Organic Reactions, 174–255. doi:10.1002/0471264180.or004.03 ) Acetaldehyde is reacted with ammonia followed by reduction in presence of hydrogen as a catalyst. The primary amine so formed further reacts with acetaldehyde. The Schiff’s base formed during the reaction is:

Read the passage given below and answer the following questions: Reductive alkylation is the term applied to the process of introducing alkyl groups into ammonia or a primary or secondary amine by means of an aldehyde or ketone in the presence of a reducing agent. The present discussion is limited to those reductive alkylations in which the reducing agent is hydrogen and a catalyst or "nascent" hydrogen, usually from a metalacid combination, most of these reductive alkylations have been carried out with hydrogen and a catalyst. The principal variation excluded is that in which the reducing agent is formic acid or one of its derivatives, this modification is known as the Leuckart reaction. The process of reductive alkylation of ammonia consists in the addition of ammonia to a carbonyl compound and reduction of the addition compound or its dehydration product. The reaction usually is carried out in ethanol solution when the reduction is to be effected catalytically Since the primary amine is formed in the presence of the aldehyde it may react in the same way as ammonia, yielding an addition compound, a Schiff's base (RCH= NCH_(2)R) and finally, a secondary amine. Similarly, the primary amine may react with the imine, forming an addition product which also is reduced to a secondary amine Finally, the secondary amine may react with either the aldehyde or the imine to give products which are reduced to tertiary amines. Similar reactions may occur when the carbonyl compound employed is a ketone. (source: Emerson, W. S. (2011). The Preparation of Amines by Reductive Alkylation. Organic Reactions, 174–255. doi:10.1002/0471264180.or004.03 ) (CH_(3)CH_(2)CH_(2))_(2)NH +CH_(3)CH_(2)CHO to P overset(2[H])to Q The ompound Q is :

One day Vabhav was performing experiments in the science laboratory based on the of chemical combination. Just then his chemistry teacher, Mr. Rajeev, came into the laboratory. Mr. Rajeev told Vaibhav that in an experiment conducted byby a class IX student when 10.6 g of sodium carbonate was reacted with 12.0g of ethanoic acid in a closed flask, then 16.4 g of sodium ethanoate, 4.4 g of carbon dioxide and an unknown mass of substances Y were produced. Mr. Rajeev asked Vaibhav to make use of this information and answer the following questions : (a) Write a word equation for the reaction which takes place on reacting sodium carbonate and ethanoic acid (b) Which is the substance Y which is produced in this reaction ? (c) What mass of substance Y is produced in this reaction ? (d) Which law of chemical combination has been made use of in calculating the mass of substance Y ? State this law (e) What values are displayed by Vaibhav in this eposide ?