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Consider a titration of potassium dichro...

Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is:

A

`3`

B

`4`

C

`5`

D

`6`

Text Solution

Verified by Experts

The correct Answer is:
D

`6Fe^(2+)+Cr_(2)O_(7)^(2-)+14H^(+)rarr 6Fe^(3+)+2Cr^(3+)+7H_(2)O`
Mohr's salt `[FeSO_(4).(NH)_(4)SO_(4).6H_(2)O]`
and dichromate reacts in `6:1` molar ratio. So, no of moles of Mohr's salt `=6`
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