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In a gravimetric determination of P, an ...

In a gravimetric determination of `P`, an aqueous solution of dihydrogen phosphate ion `[H_(2)PO_(4)^(-)]` is treated with a mixture of ammonium and magnesium ions to precipitate magnesium ammonium phosphate, `[Mg(NH_(4))PO_(4).6H_(2)O]`. This is heated and decomposed to magnesium pyrophosphate `[Mg_(2)P_(2)O_(7)]`, which is weighed. A solution of `H_(2)PO_(4)^(-)` yielded `1.054 g of Mg_(2)P_(2)O_(7)`. What weight of `NaH_(2)PO_(4)` was present originally? `(Na=23, H=1, P= 31, O=16,Mg=24)`

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The correct Answer is:
`1.1395 g`;
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Estimation of phosphorous: Second method: A known mass of compound is heated with fuming HNO_(3) or sodium peroxide (Na_(2)O_(2) in Carius tube which converts phosphorous to H_(3)PO_(4) . Magnesia mixture (MgCl_(2)+NH_(4)Cl) is then added, which gives the percipate of magnesium ammonium phosphate (MgNH_(4).PO_(4)) which on heating gives magnesium pyrophosphate (Mg_(2)P_(2)O_(7)) , which is weighted. Percentage of P =("Atomic mass of P")/("Molecular mass of " Mg_(2)P_(2)O_(7)) xx ("Molecular mass of "Mg_(2)P_(2)O_(7) xx 100)/("Mass of compound")=(62)/(222) xx("Mass of " Mg_(2)P_(2)O_(7)xx 100)/("Mass of compound") An organic compound has 6.2% of phosphorus .In the reaction sequence , all phosphorous is converted to Mg_(2)P_(2)O_(7) . Find wt. of Mg_(2)P_(2)O_(7) formed

Estimation of phosphorous: Second method: A known mass of compound is heated with fuming HNO_(3) or sodium peroxide (Na_(2)O_(2) in Carius tube which converts phosphorous to H_(3)PO_(4) . Magnesia mixture (MgCl_(2)+NH_(4)Cl) is then added, which gives the percipate of magnesium ammonium phosphate (MgNH_(4).PO_(4)) which on heating gives magnesium pyrophosphate (Mg_(2)P_(2)O_(7)) , which is weighted. Percentage of P =("Atomic mass of P")/("Molecular mass of " Mg_(2)P_(2)O_(7)) xx ("Molecular mass of "Mg_(2)P_(2)O_(7) xx 100)/("Mass of compound")=(62)/(222) xx("Mass of " Mg_(2)P_(2)O_(7)xx 100)/("Mass of compound") 0.12 gm of and organic compound containing phosphorus gave 0.22 gm of Mg_(2)P_(2)O_(7) by the usual analysis. Calculate the percentage of phosphorus in the compound.

P BAHADUR-MOLE AND EQUIVALENT CONCEPT-Exercise 9 Advanced numerical problems
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