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100 mL sample of hard water is passed th...

`100 mL` sample of hard water is passed through a column of the ion exchange resin `RH_(2)`. The water coming off the column requires `15.17 mL` of `0.0265 M NaOH` for its titration. What is the hardness of water as `"ppm"` of `Ca^(2+)`?

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The correct Answer is:
`80.40`;
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A water is said to be soft water if it produces sufficient foam with the soap and waterthat does not produce foam with soap is known as hard water. Hardness has been classified into two types (i)Temporary hardness (ii) Permanent hardness. Temporary hardness is due to presence of calcium and magnesium bicarbonate. It is simply removed by boiling as Ca(HCO_(3))_(2)overset(Delta)rarr CaCO_(3)darr+CO_(2)uarr+H_(2)O Mg(HCO_(3))_(2)overset(Delta)rarr MgCO_(3)darr+CO_(2)uarr+H_(2)O temporary hardness can also be removed by addition of slaked lime, Ca(OH)_(2) Ca(HCO_(3))_(2)+Ca(OH)_(2)to2CaCO_(3)darr+2H_(2)O permanent hardsness is due to presencce of sulphates and chlorides of Ca,Mg,etc. It is removed by washing soda as CaCl_(2)+Na_(2)CO_(3)toCaCO_(3)darr+2NaCl CaSO(4)+Na_(2)CO_(3)to CaCO_(3)darr+Na_(2)SO_(4) Permanent hardness also removed by ion exchange resin process as 2RH+Ca^(2+)toR_(2)Ca+2H^(+) 2ROH+SO_(4)^(2-)toR_(2)SO_(4)+2OH^(-) The degree of hardness of water is measured in terms of PPm of CaCO_(3) 100 PPm means 100 g of CaCO_(3) is present in 10^(6) g of H_(2)O . If any other water sample which contain 120 PPm of MgSO_(4) , hardness in terms of CaCO_(3) is equal to =100 PPm. A 200 g sample of hard water is passed through the column of cation exchange resin, in which H^(+) is exchanged by Ca^(2+) .The outlet water of column required 50mL of 0.1 M NaOH for complete neutralization.What is the hardness of Ca^(2+) ion in PPm?

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