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a' and 'b' are van der Waals' constants ...

a' and 'b' are van der Waals' constants for gases Chlorine is more easily liquefied than ethane becase .

A

a and b for `CI_(2) gt a` and b for `C_(2)H_(6)`

B

a and b for `CI_(2) gt a` and b for `C_(2)H_(6)`

C

a for `CI_(2) gt` a for `C_(2)H_(6)` but b for `CI_(2) lt b` for `C_(2)H_(6)`

D

a for `CI_(2) lt` a for `C_(2)H_(6)` but b for `CI_(2) gt` b for `C_(2)H_(6)`

Text Solution

Verified by Experts

The correct Answer is:
C

`{:(,a(dm^(3)atmmol^(-2)),b(dm^(3)mol^(-1)),,),(CI_(2),6.49,0.0562,,),(C_(2)H_(6),5.49,0.0638,,):}`
From the above values a for `CI_(2)gt` a for ethane b for ethane gt b for `CI_(2)` .
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