Home
Class 11
CHEMISTRY
The deviations from ideal gas behaviour ...

The deviations from ideal gas behaviour `PV =RT` were successfully explained by van der Waals he pointed out that it is not advisable to neglect the volume of molecules and attractions between themselves at all the conditions He proposed volume correction and pressure correction as `(V -b) and ( P+(a)/(V^(2)))` for 1 mole of gas in ideal gas equation .
The volume occupied by molecules in motion for one mole of gas at `NTP` if molecules are spherical having radius `10^(-8) cm` is .

A

`2.52cm^(3)`

B

`10.09 cm^(3)`

C

`2.52cm^(3)`

D

`10.09 cm^(3)`

Text Solution

Verified by Experts

Volume of one molecule in motion
`4 xx v_(rest) =4 xx (4)/(3) pi r^(3)`
`= 4 xx (4)/(3 xx 3.14 xx (10^(-8)) = 16.74 xx 10^(-24)`
Volume of one mole
`= 16.74 xx 10^(-24) xx 6.023 xx 10^(23) = 10.09 cm^(3)` .
Promotional Banner

Topper's Solved these Questions

  • GASEOUS STATE

    P BAHADUR|Exercise Exercise B|1 Videos
  • GASEOUS STATE

    P BAHADUR|Exercise Exercise 4|1 Videos
  • GASEOUS STATE

    P BAHADUR|Exercise Exercise 3|1 Videos
  • CHEMICAL EQUILIBRIUM

    P BAHADUR|Exercise Exercise|134 Videos
  • IONIC EQUILIBRIUM

    P BAHADUR|Exercise Exercise|85 Videos

Similar Questions

Explore conceptually related problems

The deviations from ideal gas behaviour PV =RT were successfully explained by van der Waals he pointed out that it is not advisable to neglect the volume of molecules and attractions between themselves at all the conditions He proposed volume correction and pressure correction as (V -b) and ( P+(a)/(V^(2))) for 1 mole of gas in ideal gas equation . van der Waals' equation for 'n' moles of a real gas is .

The deviations from ideal gas behaviour PV =RT were successfully explained by van der Waals he pointed out that it is not advisable to neglect the volume of molecules and attractions between themselves at all the conditions He proposed volume correction and pressure correction as (V -b) and ( P+(a)/(V^(2))) for 1 mole of gas in ideal gas equation . For a real gas PV gtRT at all pressure ranges then .

The deviations from ideal gas behaviour PV =RT were successfully explained by van der Waals he pointed out that it is not advisable to neglect the volume of molecules and attractions between themselves at all the conditions He proposed volume correction and pressure correction as (V -b) and ( P+(a)/(V^(2))) for 1 mole of gas in ideal gas equation . The compressibility factor Z is greater than unity the at STP,V_(m) in litre is .

In a gas equation, PV = RT, V refers to the volume of

Why do real gases show deviation from ideal behaviour ? Write van der Waals equation for n moles of a gas.

If v is the volume of one molecule of a gas under given conditions, then van der Waals constant b is

The van der Waals constant ……………….. Measures the forces of attraction between the molecules of a gas.

P BAHADUR-GASEOUS STATE-Exercise
  1. The deviations from ideal gas behaviour PV =RT were successfully expla...

    Text Solution

    |

  2. The deviations from ideal gas behaviour PV =RT were successfully expla...

    Text Solution

    |

  3. The deviations from ideal gas behaviour PV =RT were successfully expla...

    Text Solution

    |

  4. The deviations from ideal gas behaviour PV =RT were successfully expla...

    Text Solution

    |

  5. The Graham's law states that ''at constant pressure and temperature th...

    Text Solution

    |

  6. The Graham's law states that ''at constant pressure and temperature th...

    Text Solution

    |

  7. The Graham's law states that ''at constant pressure and temperature th...

    Text Solution

    |

  8. One litre of O(2) and one litre of h(2) are taken in a vessel of 2 lit...

    Text Solution

    |

  9. One litre of O(2) and one litre of h(2) are taken in a vessel of 2 lit...

    Text Solution

    |

  10. One litre of O(2) and one litre of h(2) are taken in a vessel of 2 lit...

    Text Solution

    |

  11. The numerical valuse of P(c),V(c),T(c) are (a)/(27b^(2)),3b,(8a)/(27...

    Text Solution

    |

  12. The numerical value of a for H(2)O is higher than C(6)H(6) H(2)O pos...

    Text Solution

    |

  13. At low pressure the van der Waals' equation is reduced to [P +(a)/(V^(...

    Text Solution

    |

  14. Molar specific heat at constant volume of an ideal diatomic gas is (5)...

    Text Solution

    |

  15. Ideal gas do not show Joule -Thoson effect as well as they cannot be l...

    Text Solution

    |

  16. Andrew's worked on a temporary gas (so called at that time) and derive...

    Text Solution

    |

  17. In a gaseous reaction the volume ratio of reactants and product is in ...

    Text Solution

    |

  18. Rate of diffusion of 1 mole CO and 2 mole N(2) in a container are same...

    Text Solution

    |

  19. Gaseous molecules heavy (e.g Br(2)) or light (H(2)) in equal number oc...

    Text Solution

    |

  20. C(p)-C(v) =R and ideal gas ((deltaU)/(deltaV))(T) =0 for an ideal g...

    Text Solution

    |