Home
Class 11
CHEMISTRY
At low pressure the van der Waals' equat...

At low pressure the van der Waals' equation is reduced to `[P +(a)/(V^(2)]]V =RT` The compressibility factor can be given as .

Text Solution

Verified by Experts

`PV+(a0V) =RT`
`:. PV =RT -(a)/(V),`
`Z = (PV)/(RT) [1-(a)/(RTV)]` .
Promotional Banner

Topper's Solved these Questions

  • GASEOUS STATE

    P BAHADUR|Exercise Exercise B|1 Videos
  • GASEOUS STATE

    P BAHADUR|Exercise Exercise 4|1 Videos
  • GASEOUS STATE

    P BAHADUR|Exercise Exercise 3|1 Videos
  • CHEMICAL EQUILIBRIUM

    P BAHADUR|Exercise Exercise|134 Videos
  • IONIC EQUILIBRIUM

    P BAHADUR|Exercise Exercise|85 Videos

Similar Questions

Explore conceptually related problems

At low pressure, the Vander Waal’s equation is reduced to

In the van der Waals equation

At high pressure , the van der Waals equation is reduced to

At low pressure, the van der Waal's equation become :

At low pressure the van der Waals' equation is written as .

At low pressures, the van der Waals equation is written as [P+(a)/(V^(2))]V=RT The compressibility factor is then equal to

At low pressures, the van der Waal's equation is written as [P + (a)/(V^(2))] V = RT The compressiblity factor is then equal to

At very high pressure, the van der Waals equation reduces to

Assertion: At low pressure van der Waal's equaiton is ruduced to [P+(a)/(V^(2))]V= RT Reason: The compressibility factor corresponding to low pressure is given by: 1-(RTV)/(a)

P BAHADUR-GASEOUS STATE-Exercise
  1. The numerical valuse of P(c),V(c),T(c) are (a)/(27b^(2)),3b,(8a)/(27...

    Text Solution

    |

  2. The numerical value of a for H(2)O is higher than C(6)H(6) H(2)O pos...

    Text Solution

    |

  3. At low pressure the van der Waals' equation is reduced to [P +(a)/(V^(...

    Text Solution

    |

  4. Molar specific heat at constant volume of an ideal diatomic gas is (5)...

    Text Solution

    |

  5. Ideal gas do not show Joule -Thoson effect as well as they cannot be l...

    Text Solution

    |

  6. Andrew's worked on a temporary gas (so called at that time) and derive...

    Text Solution

    |

  7. In a gaseous reaction the volume ratio of reactants and product is in ...

    Text Solution

    |

  8. Rate of diffusion of 1 mole CO and 2 mole N(2) in a container are same...

    Text Solution

    |

  9. Gaseous molecules heavy (e.g Br(2)) or light (H(2)) in equal number oc...

    Text Solution

    |

  10. C(p)-C(v) =R and ideal gas ((deltaU)/(deltaV))(T) =0 for an ideal g...

    Text Solution

    |

  11. A lighter gas diffuses more rapidly than a heavier gas At a given te...

    Text Solution

    |

  12. When hydrogen gas at high pressure and room temperature expands adiaba...

    Text Solution

    |

  13. The Joule -Thomson coefficient for a gas is zero at . There are no i...

    Text Solution

    |

  14. The gases He and CO(2) are very differnet in their behaviour at any te...

    Text Solution

    |

  15. All molecules of an ideal gas move with the same speed There is no a...

    Text Solution

    |

  16. Considering the van der Waals equation of state (P+a//V^(2))(V-b) =RT ...

    Text Solution

    |

  17. The hydrogen was warms up during the Joule -Thomson expansion The te...

    Text Solution

    |

  18. The heat capacities of the diatomic molecules attain a limiting value ...

    Text Solution

    |

  19. The freezing point of 0.05M urea solution is differnet from that of 0....

    Text Solution

    |

  20. Considering van der Waals equation of state for a real gas (P+n^(2)a//...

    Text Solution

    |