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Considering van der Waals equation of state for a real gas `(P+n^(2)a//V^(2))(V-nb) =nRT` the constant 'a' for `O_(2)` is less than that for `H_(2)O_(g)`
The molar mass of `O_(2)` is almost twice that of `H_(2)O` .

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Statement-1. Considering van der Waals' equation of state of NH_(3) and N_(2) [P+(a)/(V^(2))][V-b] = RT The value of van der Waals' constant for NH_(3) is more than tht for N_(2) Statement-2. Ammonia has lower molecular mass than N_(2) .

In the Van der Waals equation (P + (n^(2)a)/(V^(2))) (V-nb) = nRT , why is the term n^(2)a//V^(2) positive in sign.

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