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50 mL of 0.1M solution of a salt reacted...

`50 mL` of `0.1M` solution of a salt reacted with `25 mL` of `0.1M` solution of sodium sulphite. The half reaction for the oxidation of sulphate ion is:
`SO_(3(aq.))^(2-)+H_(2)O_((l))rarrSO_(4(aq.))^(2-)+2H_(+(aq.))+2e`
If the oxidation number of metal in the salt was `3`, what would be the new oxidation number of metal?

A

Zero

B

`1`

C

`2`

D

`4`

Text Solution

Verified by Experts

The correct Answer is:
C

Meq.of sodium sulphate`=` Meq.of salt
`25xx0.1xx2=50xx0.1xxn :. n=1` (where `n` represents valence factor for metal involving no of electrons gained)
Thus `M^(3+)+erarrM^(2+)`
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