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Which of the following has the highest b...

Which of the following has the highest boiling point ?
i. 2-Methyl pentane
ii. 2,3-Dimethyl butane
iii. 2,2-Dimethyl butane
b. What effect does branching of an alkane chain has on its melting point ?

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Which of the following has the highest boiling point ? (i) 2-Methylpentane (ii) 2, 3-Dimethylbutane (iii) 2, 2-Dimethylbutane