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Influence of pressure, temperature, conc...

Influence of pressure, temperature, concentration and addition of inert gas on a reversible chemical reaction in equilibrium can be explained by formulating the expression for equilibrium constant `K_(c)` or `K_(p)` for the equilibrium. On the other hand Le Chatelier principle can be theoretically used to explain the effect of `P`, `T` or concentration on the physical or chemical equilibrium both.
`n` moles of a reactant `A` gives one mole of `B` and `C`. If degree of dissociation of `A` is independent of initial concentration of `A`, then `n` is:

A

`1`

B

`2`

C

`3`

D

`4`

Text Solution

Verified by Experts

`underset(1-alpha)underset(1)(nA)hArrunderset(alpha//n)underset(0)(B)+underset(alpha//n)underset(0)(C)`
`:. K_(c)=(alpha^(2)*V^(n-2))/(n^(2)(1-alpha)^(n))`
If `alpha` is independent of conc., then `n-2=0 :. N=2`
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P BAHADUR-CHEMICAL EQUILIBRIUM-Comprehension
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  2. The relation between K(p) and K(c) is K(p)=K(c)(RT)^(Deltan) unit of K...

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  3. For a reaction, aA+bBhArrcC+dD, the reaction quotient Q=([C](0)^(c)[D]...

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  4. For a reaction, aA+bBhArrcC+dD, the reaction quotient Q=([C](0)^(c)[D]...

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  5. For a reaction, aA+bBhArrcC+dD, the reaction quotient Q=([C](0)^(c)[D]...

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  6. Influence of pressure, temperature, concentration and addition of iner...

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  7. Influence of pressure, temperature, concentration and addition of iner...

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  11. Influence of pressure, temperature, concentration and addition of iner...

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  12. A given sample of N(2)O(4) in a closed vessel shows 20% dissociation i...

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  13. A given sample of N(2)O(4) in a closed vessel shows 20% dissociation i...

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  14. A given sample of N(2)O(4) in a closed vessel shows 20% dissociation i...

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  15. A given sample of N(2)O(4) in a closed vessel shows 20% dissociation i...

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  16. A given sample of N(2)O(4) in a closed vessel shows 20% dissociation i...

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  17. A given sample of N(2)O(4) in a closed vessel shows 20% dissociation i...

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  18. The N(2)O(4)//NO(2(g)) equilibrium is endothermic as shown below: un...

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  19. The N(2)O(4)//NO(2(g)) equilibrium is endothermic as shown below: un...

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  20. The N(2)O(4)//NO(2(g)) equilibrium is endothermic as shown below: un...

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