The equilibrium concentraion of the reactants and products for the given equilibrium in a two litre container are shown below:
`underset(2M)(PCl_(3(g)))+underset(1M)(Cl_(2(g)))hArrunderset(4M)(PCl_(5(g)))`
(`i`) If `2` mole of `Cl_(2)` are added in the container, find the new equilibrium concentration of each.
(`ii`) If the equilibrium mixture reported initially is transferred into `4 litre` vessel, what would be the new concentration at equilibrium?

Explanation

(`i`) `[PCl_(3)]=1.5 M`, `[Cl_(2)]=1.5 M`, `[PCl_(5)]=4.5 M`,
(`ii`) `[PCl_(3)]-1.225 M`, `[Cl_(2)]=0.725 M`
`[PCl_(5)]=1.775M` ,