Home
Class 11
CHEMISTRY
Solid Ammonium carbamate dissociates as:...

Solid Ammonium carbamate dissociates as:
`NH_(2)COONH_(4)(s)hArr2NH_(3)(g)+CO_(2)(g).`
In a closed vessel, solid ammonium carbonate is in equilibrium with its dissociation products. At equilibrium, ammonia is added such that the partial pressure of `NH_(3)` at new equilibrium now equals the original total pressure. Calculate the ratio of total pressure at new equilibrium to that of original total pressure. Also find the partial pressure of ammonia gas added.

Text Solution

Verified by Experts

`(31)/(27)` ,
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    P BAHADUR|Exercise Statement:Explanation|13 Videos

  • CHEMICAL BONDING

    P BAHADUR|Exercise Exercise 7|11 Videos

  • GASEOUS STATE

    P BAHADUR|Exercise Exercise -9|1 Videos

Similar Questions

Explore conceptually related problems

A(s)hArr2B(g)+C(g) The above equilibrium was established by initially taking A(s) only. At equilibrium, B is removed so that its partial pressure at new equilibrium becomes 1//3^(rd) of original total preswsure. Ratio of total pressure at new equilibrium and at initial equilibrium will be :

Solid ammonium carbamate dissociated according to the given reaction NH_2COONH_4(s) hArr 2NH_3(g) +CO(g) Total pressure of the gases in equilibrium is 5 atm. Hence K_p .

A solid A dissociates to give B and C gases as shown, A(s) hArr 2B(g)+3C(g) At equilibrium some B(g) is introduced keeping volume constant so that pressure of B of new equilibrium becomes equal to 8/(5sqrt2) times original total pressure calculate ratio of initial equilibrium pressure of C to that of its final pressure

P BAHADUR-CHEMICAL EQUILIBRIUM-Exercise
  1. To the system, LaCl(3)(s)+H(2)O(g) hArr LaClO(s)+2HCL(g)-"Heat" alre...

    Text Solution

    |

  2. At a certain temperature , K(p) for dissociation of solid CaCO(3) is 4...

    Text Solution

    |

  3. Solid Ammonium carbamate dissociates as: NH(2)COONH(4)(s)hArr2NH(3)(...

    Text Solution

    |

  4. In the preparation of CaO from CaCO(3) using the equilibrium, CaCO(3...

    Text Solution

    |

  5. A vessel of 2.50 litre was filled with 0.01 mole of Sb(2)S(3) and 0.01...

    Text Solution

    |

  6. Sulphide ions in alkaline solution react with solid sulphur to form po...

    Text Solution

    |

  7. Calculate K(c ) for the reaction KI + I(2) hArr KI(3). Given that init...

    Text Solution

    |

  8. To 500 mL of 0.150 M AgNO(3) solution were added 500 mL of 1.09 M Fe^(...

    Text Solution

    |

  9. A saturated solution of iodine in water contain 0.330g I(2) per litre....

    Text Solution

    |

  10. For the equilibrium: LiCl.3NH(3(s))hArrLiCl.NH(3(s))+2NH(3), K(p)=9 ...

    Text Solution

    |

  11. Consider the sublimation of mothballs at 27^(@)C in a vessel having di...

    Text Solution

    |

  12. Would 1% CO(2) in air be sufficient to prevent any loss in weight when...

    Text Solution

    |

  13. Under what pressure conditions CuSO(4).5H(2)O be efforescent at 25^(@)...

    Text Solution

    |

  14. For the reaction, 2Fe((aq.))^(3+)+Hg((aq.))^(2+)hArr2Fe((aq.))^(2+)+...

    Text Solution

    |

  15. When NO and NO(2) are mixed, the following equilibria are readily obta...

    Text Solution

    |

  16. Two solid compounds A and B dissociate into gaseous products at 20^(@)...

    Text Solution

    |

  17. Solid NH(4)I on rapid heating in a closed vessel at 357^(@)C dvelops a...

    Text Solution

    |

  18. In a reaction at equilibrium, 'x' mole of reactant A decompose to give...

    Text Solution

    |

  19. For a reaction, aA+bBhArrcC+dD, the reaction quotient Q=([C](0)^(c)[D]...

    Text Solution

    |

  20. N(2) and O(2) combine at a given temperature to produce NO. At equilib...

    Text Solution

    |