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For, H(3)PO(4)+H(2)OhArrH(3)O^(+)+H(2)PO...

For, `H_(3)PO_(4)+H_(2)OhArrH_(3)O^(+)+H_(2)PO_(4)^(-), K_(a_(1))`
`H_(2)PO_(4)+H_(2)OhArrH_(3)O^(+)+HPO_(4)^(2-), K_(a_(2))`
`HPO_(4)^(2-)+H_(2)OhArrH_(3)O^(+)+PO_(4)^(3-), K_(a_(3))`
The correct order of `K_(a)` values is:

A

`K_(a_(1))gtK_(a_(2))ltK_(a_(3))`

B

`K_(a_(1))ltK_(a_(2))ltK_(a_(3))`

C

`K_(a_(1))gtK_(a_(2))gtK_(a_(3))`

D

`K_(a_(1))ltK_(a_(2))gtK_(a_(3))`

Text Solution

Verified by Experts

The correct Answer is:
C

The dissociation constant for different ateps dissociation of weak polyrotic acid decreases continuously, i.e., `K_(a_(1))gtK_(a_(2))gtK_(a_(3))`
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For H_(3)PO_(4) , H_(3)PO_(4) hArr H_(2)PO_(4)^(-) + H^(+) (K_(1)) H_(2)PO_(4)^(-) hArr HPO_(4)^(2-) + H^(+) (K_(2)) HPO_(4)^(2-) hArr PO_(4)^(3-) + H^(+) (K_(3)) then

For ortho phosphoric acid, H_3PO_4(aq)+H_2O(aq) to H_3O^(+)(aq)+H_2PO_4^(-)(aq),K_(a_1) H_2PO_4^-(aq)+H_2O(aq) to H_3O^(+)(aq)+H_2PO_4^(-)(aq),K_(a_2) HPO_4^(2-)(aq)+H_2O(aq) to H_3O^(+)(aq)+PO_3^(4)(aq),K_(a_3) The correct order of K_a values is :

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H_(3)underline(P)O_(5)+H_(2)O to H_(3)PO_(4)+H_(2)O_(2)

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H_(4)underline(P_(2))O_(7)+H_(2)O to 2H_(3)PO_(4)

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