Home
Class 11
CHEMISTRY
One mole of an ideal mono-atomic gas is ...

One mole of an ideal mono-atomic gas is taken round cyclic process `ABCD` as shown in figure below. Calculate

Text Solution

Verified by Experts

Path `AB` is isochoric `(w_(1)=0)`, path `BC` is isothermal `(w_(2)=-ve)`, path `CA` is isobaric `(w_(3)=+ve)`
Total work done by gas `(w)`
`=w_(1)+w_(2)+w_(3)`
`=0+2.303nRT"log"(V_(B))/(V_(C))+P(V_(C)-V_(A))`
`=0+2.303P_(B)V_(B)"log"(V_(B))/(V_(C))+P(V_(C)-V_(A))`
`=2.303xx3P_(0)V_(0)"log"(V_(0))/(2V_(0))+P_(0)(2V_(0)-V_(0))`
`=-2P_(0)V_(0)+P_(0)V_(0)=-P_(0)V_(0)`
Also, `w_(2)=-2P_(0)V_(0)` and `w_(3)=P_(0)V_(0)`
also, For the path `AB`, ie. isochoric
`q_(1)=nxxC_(P)xx(T_(B)-T_(A))=1xx3/2R[(P_(B)V_(B)-P_(A)V_(A))/R]`
`=3/2[3P_(0)V_(0)-P_(0)V_(0)]=+3P_(0)V_(0)`
For the path `CA`, i.e., isochoric:
`q_(3)=nxxC_(P)xx(T_(A)-T_(B))`
`=1xx5/2R[(P_(A)V_(A)-P_(B)V_(B))/R]`
`=5/2[P_(0)V_(0)-2P_(0)V_(0)]`
`q_(3)=-5/2 P_(0)V_(0)`
Also net heat absorbed `=3P_(0)V_(0)-5/2P_(0)V_(0)-=(P_(0)V_(0))/2`
`:. q_("net")=(P_(0)V_(0))/2`
Also, `(P_(0)V_(0))/(T_(1))=(3P_(0)V_(0))/(T_(2)):. T_(2)=3T_(1)=(3P_(0)V_(0))/R`
Promotional Banner

Topper's Solved these Questions

  • THERMOCHEMISTRY

    P BAHADUR|Exercise Exercise 9 Advance numerical problems|31 Videos

Similar Questions

Explore conceptually related problems

One mole of an ideal monoatomatic gas is taken round the cylic process ABCA as shown Then

One mole of ideal monoatomic gas is taken round the cyclic process as shown in figure. The heat rejected by the gas in the path is ………...and the heat absorbed by the gas in the path AB is ………...........

One mole of ideal monoatmic gas is carried throught the reversible cyclic process as shown in figure. Calculate net heat absorbed by the gas in the path BC

One mole of monoatomic has was taken through a cyclic process as shown in figure. Calculate (dq_("rev"))/(T)

One mole of an ideal gas is taken through the cyclic process ABCDA, as shown in (figure). Using the graph, calculate (i) Work done in the processes ArarrB, BrarrC, CrarrD and DrarrA (ii) Work done in complete cycle ABCDA (iii) Heat rejected by the gas in one complete cycle.

One mole of an ideal monoatomic gas undergoes a cyclic process as shown in figure . Temperature at point 1 = 300K and process 2-3 is isothermal . . Net work done by gas in complete cycle is

P BAHADUR-THERMODYNAMICS-Exercise
  1. A sample of argon gas at 1atm pressure and 27^@C expands reversibly an...

    Text Solution

    |

  2. One mole of an ideal gas is heated at constant pressure from 0^(@)C to...

    Text Solution

    |

  3. One mole of an ideal mono-atomic gas is taken round cyclic process ABC...

    Text Solution

    |

  4. Derive a relation showing reversible work of expansion from volume V1 ...

    Text Solution

    |

  5. What work is to be done on 2 mole of a perfect gas at 27^@C if it is c...

    Text Solution

    |

  6. Calculate the maximum work done in expanding 16g of oxygen at 300K occ...

    Text Solution

    |

  7. Calculateq, W, DeltaU and DeltaH for the isothermal reversible expansi...

    Text Solution

    |

  8. Calculate the change of entropy, Delta(r)S^(Theta) at 298K for the rea...

    Text Solution

    |

  9. The enthalpy of vaporisation of liquid diethly ether -(C2H5)2O, is 26....

    Text Solution

    |

  10. Ethanol boils at 78.4^@C and the enthalpy of vaporisation of ethanol i...

    Text Solution

    |

  11. Calculate the entropy change for the conservation of following: (a) 1g...

    Text Solution

    |

  12. Given S^@ for C("Graphite"), H(2(g)) and CH(4(g)) are 5.70, 130.7 and ...

    Text Solution

    |

  13. In a fuel cell, methanol if used as fuel and oxygen gas is used as an ...

    Text Solution

    |

  14. For the water gas reaction: C(s) +H(2)O(g) hArr CO(g) +H(2)(g) the...

    Text Solution

    |

  15. The standard Gibbs free energies for the reaction at 1773K are given b...

    Text Solution

    |

  16. Predict whether it is possible or not to reduce magnesium oxide using ...

    Text Solution

    |

  17. Calculate DeltaG^(Theta) for the conversion of oxygen to ozone, ((3)/(...

    Text Solution

    |

  18. Calculate the equilibrium constant Kp for the reaction given below if ...

    Text Solution

    |

  19. Calculate the value of DeltaG at 700K for the reaction, nX to mB. Give...

    Text Solution

    |

  20. Calculated the Gibbs energy change on dissolving one mole of sodium ch...

    Text Solution

    |