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Standard enthalpy and standard entropy c...

Standard enthalpy and standard entropy change for the oxidation of `NH_(3)` at `298K` are `-382.64KJ mol^(-1)` and `145.6Jmol^(-1)` respectively. Standard free energy change for the same reaction at `298K` is

A

`-439.3 k J mol^(-1)`

B

`221.1 kJ mol^(-1)`

C

`-339.3 kJ mol^(-1)`

D

`-526.2 kJ mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

`DeltaG^(@)=DeltaH^(@)-TDeltaS^(@)`
`=-382.64-298xx(-145.6xx10^(-3))`
`=-339.3 k J mol^(-1)`
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P BAHADUR-THERMODYNAMICS-Exercise
  1. DeltaH and DeltaS for the system H2O((l))hArr H2O((g)) at 1atm are 40....

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  2. Two moles of ideal gas at 27^(@)C temperature is expanded reversibly f...

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  3. Standard enthalpy and standard entropy change for the oxidation of NH(...

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  4. One mole of an ideal gas at 27^@C expanded isothermally from an initia...

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  5. The molar heat capacity of water at constant pressure P , is 75JK^(-1)...

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  6. An ideal gas heat engine operates in Carnot cycle between 227^@C and 1...

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  7. Which of the following graphs given below show (s) adiabatic process?

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  8. In an adiabatic expansion of air (assume it a mixture of N2 and O2), t...

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  9. A monoatomic gas is suddenly compressed to 1//8 of its original volume...

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  10. The process of evaporation of a liquid is accompanied by :

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  11. All natural processes proceed spontaneously in a direction which :

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  12. Which of the following is (are) correct an adiabatic process?

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  13. If q is the amount of heat absorbed by the system and W the amount of ...

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  14. Select the correct statements:

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  15. In a reaction, DeltaH and DeltaS both are more than zero. In which of ...

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  16. In which reaction(s), DeltaS in negative?

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  17. For the adiabatic expansion of an ideal gas:

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  18. The internal energy (U) of an ideal gas decreases by the same amount a...

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  19. Which has/have a positive value (s) of DeltaH?

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  20. Which of the following statements is (are) correct?

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