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In an irreversible process taking place ...

In an irreversible process taking place at constant `T` and `P` and in which only pressure-volume work is being done, the change in Gibbs free energy `(dG)` and the change in entropy `(dS)` satisfy the criteria

A

`(dS)_(V,U)=0,(dG)_(T,P)=0`

B

`(dS)_(V,U)=0,(dG)_(T,P)=+ve`

C

`(dS)_(V,U)=-ve,(dG)_(T,P)=-ve`

D

`(dS)_(V,U)=+ve,(dG)_(T,P)=-ve`

Text Solution

Verified by Experts

The correct Answer is:
d
For a spontaneous change (work is beign done by the system) `(dG)_(T,P)=-ve` and `(dS)_(V,U)=+ve`
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