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Statement: The thermodynamics functions ...

Statement: The thermodynamics functions which determines the spontaneity of a process is the free energy. For a process to be spontaneous, the change in free energy must be negative.
Explanation:The change in free energy is related to the change in enthalpy and change in entropy. the change in entropy for a process must be always positive if it is spontaneous.

A

`S` is correct but `E` is wrong.

B

`S` is wrong but `E` are correct and `E`

C

Both `S` and `E` are correct but `E` is correct explanation of `S`.

D

Both `S` and `E` are correct but `E` is not correct explanation of `S`.

Text Solution

Verified by Experts

The correct Answer is:
a

The change in entropy for spontaneous reaction may be positive or negative.
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Assertion (A): The thermodynamic factor which determines the spontaneity of a process is the free energy. For a process to be spontaneous the free energy must be-ve. Reason (R ) : The change in free energy is related to the change in a process must always be positive if its is spontaneous.

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Free energy change is related to enthalpy and entropy changes as:

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2nd Law of thermodynamics | Spontaneity of a reaction | Gibbs free energy

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