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Assertion (A): For every chemical reacti...

Assertion (A): For every chemical reaction at equilibrium, standard Gibbs enegry of the reaction is zero.
Reason (R ) : At constant temperature and pressure chemical reactions are spontaneous in the direction of the decreasing Gibbs energy.

A

`S` is correct but `E` is wrong.

B

`S` is wrong but `E` are correct and `E`

C

Both `S` and `E` are correct but `E` is correct explanation of `S`.

D

Both `S` and `E` are correct but `E` is not correct explanation of `S`.

Text Solution

Verified by Experts

The correct Answer is:
b

AT equilibrium `DeltaG=0`, but standard Gibbs energy `(DeltaG^(2))` of a reaction may or may not be zero. For reaction to be spontaneousn `DeltaG`(Gibbs energy) should be more negative, i.e., `DeltaGgt0`.
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Select correct statements: S_(1) : For every chemical reaction at equilibrium , standard gibbs energy of reaction is zero S_(2) : At constant temperature and pressure , chemical reactions are spontaneous in the direction of decreasing gibbs energy. S_(3) : Spontancity is related to change in entropy if universe.

Statement -1: For every chmical reaction at equilibrium , standard Gidds energy of reaction is zero Statement-2: At constant temperature and pressure , chemical reactions are spontaneious in the direction of decreasing gibbs energy.

In the following questions , a statement of assertion (A) is followed by a statement of reason (R). A : For every chemical reaction at equilibrium, the value of standard Gibbs free energy change is zero. R: At constant temperature and pressure for a reaction that direction is preferred for which Gibbs free energy increases.

P BAHADUR-THERMODYNAMICS-Exercise
  1. Statement: The thermodynamics functions which determines the spontanei...

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  2. Statement: In the case of an ideal gas the changes in Gibbs and Helmho...

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  3. Assertion (A): For every chemical reaction at equilibrium, standard Gi...

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  4. Assertion (A) : There is a natural asymmetry between converting work t...

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  5. A gas occupies 2L at STP. It is provided 300J heat so that it volume b...

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  6. Calculate the work done during the process, when one mole of gas is al...

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  7. 2.8g of N(2) gas at 300K and 20atm was allowed to expand isothermally ...

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  8. At 27^(@)C, one mole of an ideal gas is compressed isothermally and re...

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  9. One mole of an ideal gas is heated at constant pressure from 0^(@)C to...

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  10. 1 mol of an ideal gas at 25^(@)C is subjected to expand reversibly 10 ...

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  11. An insulated container is divided into two equal portions. One portion...

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  12. The temperature of a bomb calorimeter was found to rise by 1.617K when...

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  13. A flask of 1L having NH(3)(g) at 2.0atm and 200K is connected with the...

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  14. The specific heat of a liquid was measured by placing 100 g of the liq...

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  15. A sample of 3.0 mole of perfect gas at 200 K and 2.0 atm is compressed...

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  16. One mole of a monoatomic ideal gas is heated at constant pressure from...

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  17. Calculate the final temperature of a sample of CO(2) gas(16g) that is ...

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  18. One mole of a perfect gas is put through a cycle consisting of the fol...

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  19. 1g of water changes from liquid to vapour phase at constant pressure o...

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  20. The given figure shown a change of state A to state C by two paths ABC...

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