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The correct order for triple bond energy...

The correct order for triple bond energy in `CO, N_2, CN` and `C-=C` is ,

A

` C -= O gt N-= Ngt C-= N gt C-=C`

B

`N -=N gt C-= O gt C-= Cgt C -=N`

C

`N -=N gt C-= O gtN-= Cgt C -=C`

D

`N -=N gt C-= O gtC= Cgt C -=C`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order for triple bond energy in `CO`, `N2`, `CN`, and `C≡C`, we can follow these steps: ### Step 1: Understand the Concept of Bond Energy Bond energy is the amount of energy required to break a bond between two atoms. Generally, shorter bonds (which occur between smaller atoms) have higher bond energies due to the stronger attraction between the nuclei of the bonded atoms. ### Step 2: Analyze the Molecules - **`CO` (Carbon Monoxide)**: This molecule has a triple bond between carbon and oxygen. The bond is polar due to the difference in electronegativity between carbon and oxygen. - **`N2` (Nitrogen Gas)**: This molecule has a triple bond between two nitrogen atoms. Nitrogen atoms are of the same size and have a strong bond due to effective overlap of p-orbitals. - **`CN` (Cyanide Ion)**: This molecule also has a triple bond, with carbon and nitrogen. The bond is polar, but the electronegativity difference is less than that in `CO`. - **`C≡C` (Acetylene)**: This molecule has a triple bond between two carbon atoms. Carbon atoms are relatively small, leading to a strong bond. ### Step 3: Compare Bond Energies 1. **`CO`**: The bond energy is high due to the polar nature of the bond and the small size of the atoms involved. 2. **`N2`**: The bond energy is also high due to the effective overlap of p-orbitals, but it is less than that of `CO`. 3. **`CN`**: The bond energy is lower than `CO` and `N2` due to less polarity and the larger size of carbon compared to nitrogen. 4. **`C≡C`**: The bond energy is lower than that of `CO`, `N2`, and `CN` due to the lack of polarity and the fact that both atoms are the same. ### Step 4: Establish the Order Based on the analysis: - `CO` has the highest bond energy. - `N2` follows next. - `CN` comes after `N2`. - `C≡C` has the lowest bond energy. Thus, the correct order for triple bond energy in `CO`, `N2`, `CN`, and `C≡C` is: **`CO > N2 > CN > C≡C`** ### Final Answer The correct order for triple bond energy is: **`CO > N2 > CN > C≡C`** ---

To determine the correct order for triple bond energy in `CO`, `N2`, `CN`, and `C≡C`, we can follow these steps: ### Step 1: Understand the Concept of Bond Energy Bond energy is the amount of energy required to break a bond between two atoms. Generally, shorter bonds (which occur between smaller atoms) have higher bond energies due to the stronger attraction between the nuclei of the bonded atoms. ### Step 2: Analyze the Molecules - **`CO` (Carbon Monoxide)**: This molecule has a triple bond between carbon and oxygen. The bond is polar due to the difference in electronegativity between carbon and oxygen. - **`N2` (Nitrogen Gas)**: This molecule has a triple bond between two nitrogen atoms. Nitrogen atoms are of the same size and have a strong bond due to effective overlap of p-orbitals. ...
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P BAHADUR-CHEMICAL BONDING-Exercise2A
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  2. Which statement is wrong about H2O ?

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  3. The correct order for triple bond energy in CO, N2, CN and C-=C is ,

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  4. In NO(3)^(-) ion, the number of bond pair and lone pair of electrons o...

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  5. Which of the following molecule froms linear polymeric structure due t...

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  6. The correct roder o fincreasing C-O bond lengths in CO, CO3^(2-) and ...

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  7. Among the following which has resonating structure ?

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  8. For which crystalline substance does the solubility in water increase ...

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  9. Which among the following is true ?

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  10. During the formation of a molecular orbital from atomic orbitral , th...

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  11. The shapes of PCl4^+, PCl4^- and AsCl4 are respectively :

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  12. Which of the following paires of elements for oxideas of polyanions a...

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  13. N -O -N bond andle is maximum in :

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  14. Which is not a permissible resonating structure ?

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  15. Which pair represents canonical from ?

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  16. Which of the following would have permanent dipple moment ?

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  17. The correct order of increasing covalent charactre is :

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  18. Which one of the following orders is not correct in accordance whith ...

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  19. The electronegaivity difference between N and F is greater than that b...

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  20. In which of the following moleucles are all the bonds not equal ?

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